Schedule
Schedule I – PBT and vPvB Assessment Criteria
Criteria for the Identification of Persistent, Bio-accumulative and Toxic (PBT) and very Persistent and very Bio-accumulative (vPvB) Substances
1.1. PBT Substances
A substance that fulfils the persistence, bioaccumulation and toxicity criteria of Sections 1.1.1, 1.1.2 and 1.1.3 shall be considered a PBT substance
1.1.1. Persistence
A substance fulfils the persistence criterion in any of the following situations:
(a) the degradation half-life in marine water is higher than 60 days; or
(b) the degradation half-life in fresh or estuarine water is higher than 40 days; or
(c) the degradation half-life in marine sediment is higher than 180 days; or
(d) the degradation half-life in fresh or estuarine water sediment is higher than 120 days; or
(e) the degradation half-life in soil is higher than 120 days.
1.1.2. Bioaccumulation
A substance fulfils the bioaccumulation criterion when the bioconcentration factor in aquatic species is higher than 2000.
1.1.3. Toxicity
A substance fulfils the toxicity criterion in any of the following situations:
(a) the long-term no-observed effect concentration (NOEC) or EC10 for marine or freshwater organisms is less than 0.01 mg/l; or
(b) the substance meets the criteria for classification as carcinogenic (category 1A or 1B), germ cell mutagenic (category 1A or 1B), or toxic for reproduction (category 1A, 1B, or 2); or
(c) there is other evidence of chronic toxicity, as identified by the substance meeting the criteria for classification: specific target organ toxicity after repeated exposure (STOT RE category 1 or 2).
1.2. vPvB Substances
A substance that fulfils the persistence and bio-accumulation criteria of Sections 1.2.1 and 1.2.2 shall be considered a vPvB Substance
1.2.1. Persistence
A substance fulfils the ‗very persistent‘ criterion in any of the following situations:
(a) the degradation half-life in marine, fresh or estuarine water is higher than 60 days; or
(b) the degradation half-life in marine, fresh or estuarine water sediment is higher than 180 days; or
(c) the degradation half-life in soil is higher than 180 days.
1.2.2. Bioaccumulation
A substance fulfils the ‗very bio-accumulative‘ criterion when the bioconcentration factor in aquatic species is higher than 5000.
Schedule II – List of Priority Substances required to be Registered
Sr. No. | Chemical Name | CAS No. | Hazard Category |
1 | Diarsenic trioxide | 1327-53-3 | Carcinogenic |
2 | Diarsenic pentaoxide | 1303-28-2 | Carcinogenic |
3 | Lead chromate | 7758-97-6 | Carcinogenic |
4 | Lead sulfochromate yellow | 1344-37-2 | Carcinogenic |
5 | Lead chromate molybdate sulfate red | 12656-85-8 | Carcinogenic |
6 | Chromic acid | 7738-94-5 | Carcinogenic |
7 | Dichromic acid | 13530-68-2 | Carcinogenic |
8 | Sodium dichromate | 10588-01-9 | Carcinogenic |
9 | Potassium dichromate | 7778-50-9 | Carcinogenic |
10 | Ammonium dichromate | 7789-09-5 | Carcinogenic |
11 | Potassium chromate | 7789-00-6 | Carcinogenic |
12 | Sodium chromate | 7775-11-3 | Carcinogenic |
13 | Formaldehyde, oligomeric reaction products with aniline | 25214-70-4 | Carcinogenic |
14 | 1,2-dichloroethane (EDC) | 107-06-2 | Carcinogenic |
15 | Dichromium tris(chromate) | 24613-89-6 | Carcinogenic |
16 | Strontium chromate | 7789-06-2 | Carcinogenic |
17 | Potassium hydroxyoctaoxodizincatedichromate | 11103-86-9 | Carcinogenic |
18 | Pentazinc chromate octahydroxide | 49663-84-5 | Carcinogenic |
19 | 1,2-Benzenedicarboxylic acid, di-C6-8-branched alkyl esters, C7-rich | 71888-89-6 | Toxic for reproduction |
20 | 1,2-Benzenedicarboxylic acid, di-C7-11-branched and linear alkyl esters | 68515-42-4 | Toxic for reproduction |
21 | 1,2-Benzenedicarboxylic acid, dipentyl ester, branched and linear | 84777-06-0 | Toxic for reproduction |
22 | Anthracene oil | 90640-80-5 | Carcinogenic |
23 | Pitch, coal tar, high-temp. | 65996-93-2 | Carcinogenic |
24 | 20-(4-nonylphenoxy)-3,6,9,12,15,18hexaoxaicosan-1-ol | 27942-27-4 | Endocrine disrupting properties |
25 | 4-Nonylphenol, branched, ethoxylated | 127087-87- 0 | Endocrine disrupting properties |
26 | 26-(nonylphenoxy)-3,6,9,12,15,18,21,24octaoxahexacosan-1-ol | 26571-11-9 | Endocrine disrupting properties |
27 | Diisohexyl phthalate | 71850-09-4 | – |
28 | 2-methyl-1-(4-methylthiophenyl)-2morpholinopropan-1-one | 71868-10-5 | – |
29 | 2-benzyl-2-dimethylamino-4’morpholinobutyrophenone | 119313-12- 1 | – |
30 | Phenol, 4-nonyl-, phosphite (3:1) | 3050-88-2 | – |
31 | Tris(nonylphenyl) phosphite | 26523-78-4 | – |
32 | 4-tert-butylphenol | 98-54-4 | – |
33 | 2-methoxyethyl acetate | 110-49-6 | – |
34 | 2,3,3,3-tetrafluoro-2- (heptafluoropropoxy)propionyl fluoride | 2062-98-8 | – |
35 | Ammonium 2,3,3,3-tetrafluoro-2- (heptafluoropropoxy)propanoate | 62037-80-3 | – |
36 | Potassium 2,3,3,3-tetrafluoro-2- (heptafluoropropoxy)propionate | 67118-55-2 | – |
37 | 2,3,3,3-tetrafluoro-2- (heptafluoropropoxy)propionic acid | 13252-13-6 | – |
38 | Pyrene | 129-00-0 | – |
39 | Phenanthrene | 85-01-8 | – |
40 | Fluoranthene | 206-44-0 | – |
41 | Benzo[k]fluoranthene | 207-08-9 | – |
42 | 2,2-bis(4′-hydroxyphenyl)-4-methylpentane | 6807-17-6 | – |
43 | 1,7,7-trimethyl-3- (phenylmethylene)bicyclo[2.2.1]heptan-2-one | 15087-24-8 | – |
44 | Terphenyl, hydrogenated | 61788-32-7 | – |
45 | Octamethylcyclotetrasiloxane | 556-67-2 | – |
46 | Lead | 7439-92-1 | – |
47 | Ethylenediamine | 107-15-3 | – |
48 | Dodecamethylcyclohexasiloxane | 540-97-6 | – |
49 | Disodium octaborate | 12008-41-2 | – |
50 | Dicyclohexyl phthalate | 84-61-7 | – |
51 | Decamethylcyclopentasiloxane | 541-02-6 | – |
52 | Benzo[ghi]perylene | 191-24-2 | – |
53 | Benzene-1,2,4-tricarboxylic acid 1,2 anhydride | 552-30-7 | – |
54 | Formaldehyde, reaction products with branched and linear heptylphenol, carbon disulfide and hydrazine | 93925-00-9 | – |
55 | Chrysene | 218-01-9 | – |
56 | Cadmium nitrate | 10325-94-7 | – |
57 | Cadmium hydroxide | 21041-95-2 | – |
58 | Cadmium carbonate | 513-78-0 | – |
59 | Benz[a]anthracene | 56-55-3 | – |
60 | 1,6,7,8,9,14,15,16,17,17,18,18dodecachloropentacyclo[12.2.1.16,9.02,13.05,10] octadeca-7,15-diene | 13560-89-9 | – |
61 | Perfluorohexane-1-sulphonic acid | 355-46-4 | – |
62 | Tridecafluorohexanesulphonic acid, compound with 2,2′-iminodiethanol (1:1) | 70225-16-0 | – |
63 | Ammonium perfluorohexane-1-sulphonate | 68259-08-5 | – |
64 | Potassium perfluorohexane-1-sulphonate | 3871-99-6 | – |
65 | p-(1,1-dimethylpropyl)phenol | 80-46-6 | – |
66 | Nonadecafluorodecanoic acid | 335-76-2 | – |
67 | Decanoic acid, nonadecafluoro-, sodium salt | 3830-45-3 | – |
68 | Ammonium nonadecafluorodecanoate | 3108-42-7 | – |
69 | Phenol, heptyl derivs. | 72624-02-3 | – |
70 | 4-heptylphenol | 1987-50-4 | – |
71 | 4,4′-isopropylidenediphenol | 80-05-7 | – |
72 | Benzo[def]chrysene (Benzo[a]pyrene) | 50-32-8 | – |
73 | Perfluorononan-1-oic-acid | 375-95-1 | – |
74 | Sodium salts of perfluorononan-1-oic-acid | -, 21049-39- 8 | – |
75 | Ammonium salts of perfluorononan-1-oic-acid | -, 4149-60-4 | – |
76 | Nitrobenzene | 98-95-3 | – |
77 | 2-(2H-benzotriazol-2-yl)-4-(tert-butyl)-6-(secbutyl)phenol (UV-350) | 36437-37-3 | – |
78 | 2,4-di-tert-butyl-6-(5-chlorobenzotriazol-2yl)phenol (UV-327) | 3864-99-1 | – |
79 | 1,3-propanesultone | 1120-71-4 | – |
80 | reaction mass of 5-(sec-butyl)-2-(2,4dimethylcyclohex-3-en-1-yl)-5-methyl-1,3dioxane and 5-(sec-butyl)-2-(4,6dimethylcyclohex-3-en-1-yl)-5-methyl-1,3dioxane | 117933-89- 8 | – |
81 | 2-(2,4-Dimethylcyclohex-3-ene-1-yl)-5-methyl- (1-methylpropyl)-1,3-dioxane | 117933-89- 8 | – |
82 | 1,2-Benzenedicarboxylic acid, mixed decyl and hexyl and octyl diesters | 68648-93-1 | – |
83 | 1,2-Benzenedicarboxylic acid, di-C6-10-alkyl esters | 68515-51-5 | – |
84 | Cadmium sulphate | 10124-36-4, 31119-53-6 | – |
85 | Cadmium fluoride | 7790-79-6 | – |
86 | 2-ethylhexyl 10-ethyl-4,4-dioctyl-7-oxo-8-oxa- 3,5-dithia-4-stannatetradecanoate (DOTE) | 15571-58-1 | – |
87 | 2-benzotriazol-2-yl-4,6-di-tert-butylphenol (UV- 320) | 3846-71-7 | – |
88 | 2-(2H-benzotriazol-2-yl)-4,6-ditertpentylphenol (UV-328) | 25973-55-1 | – |
89 | Sodium peroxometaborate | 7632-04-4 | – |
90 | Perboric acid, sodium salt | 11138-47-9 | – |
91 | Sodium perborate | 15120-21-5 | – |
92 | Cadmium chloride | 10108-64-2 | – |
93 | 1,2-Benzenedicarboxylic acid, dihexyl ester, branched and linear | 68515-50-4 | – |
94 | Trixylyl phosphate | 25155-23-1 | – |
95 | Lead di(acetate) | 301-04-2 | – |
96 | Imidazolidine-2-thione (2-imidazoline-2-thiol) | 96-45-7 | – |
97 | Disodium 4-amino-3-[[4′-[(2,4diaminophenyl)azo][1,1′-biphenyl]-4-yl]azo] -5hydroxy-6-(phenylazo)naphthalene-2,7disulphonate (C.I. Direct Black 38) | 1937-37-7 | – |
98 | Disodium 3,3′-[[1,1′-biphenyl]-4,4’diylbis(azo)]bis(4-aminonaphthalene-1sulphonate) (C.I. Direct Red 28) | 573-58-0 | – |
99 | Dihexyl phthalate | 84-75-3 | – |
100 | Cadmium sulphide | 1306-23-6 | – |
101 | Pentadecafluorooctanoic acid (PFOA) | 335-67-1 | – |
102 | Dipentyl phthalate (DPP) | 131-18-0 | – |
103 | Cadmium oxide | 1306-19-0 | – |
104 | Cadmium | 7440-43-9 | – |
105 | Ammonium pentadecafluorooctanoate (APFO) | 3825-26-1 | – |
106 | 2-[2-[2-[2-(4- nonylphenoxy)ethoxy]ethoxy]ethoxy]ethanol | 7311-27-5 | – |
107 | 20-(4-nonylphenoxy)-3,6,9,12,15,18hexaoxaicosan-1-ol | 27942-27-4 | – |
108 | 4-Nonylphenol, ethoxylated | 26027-38-3 | – |
109 | Nonylphenol, branched, ethoxylated | 68412-54-4 | – |
110 | Nonylphenol, ethoxylated | 9016-45-9 | – |
111 | 2-[2-(4-nonylphenoxy)ethoxy]ethanol | 20427-84-3 | – |
112 | 26-(4-nonylphenoxy)-3,6,9,12,15,18,21,24- Octaoxahexacosan-1-ol | 14409-72-4 | – |
113 | 26-(nonylphenoxy)-3,6,9,12,15,18,21,24octaoxahexacosan-1-ol | 26571-11-9 | – |
114 | 4-Nonylphenol, branched, ethoxylated | 127087-87- 0 | – |
115 | 2-{2-[4-(3,6-dimethylheptan-3yl)phenoxy]ethoxy}ethanol | 1119449- 38-5 | – |
116 | Poly(oxy-1,2-ethanediyl), a-(nonylphenyl)-whydroxy- (CAS 9016-45-9) | 9016-45-9 | – |
117 | Isononylphenol, ethoxylated | 37205-87-1 | – |
118 | 2-[4-(3,6-dimethylheptan-3-yl)phenoxy]ethanol | 1119449- 37-4 | – |
119 | Trilead dioxide phosphonate | 12141-20-7 | – |
120 | Trilead bis(carbonate) dihydroxide | 1319-46-6 | – |
121 | Tricosafluorododecanoic acid | 307-55-1 | – |
122 | Tetralead trioxide sulphate | 12202-17-4 | – |
123 | Tetraethyllead | 78-00-2 | – |
124 | Sulfurous acid, lead salt, dibasic | 62229-08-7 | – |
125 | Silicic acid, lead salt | 11120-22-2 | – |
126 | Silicic acid (H2Si2O5), barium salt (1:1), leaddoped | 68784-75-8 | – |
127 | Pyrochlore, antimony lead yellow | 8012-00-8 | – |
128 | Pentalead tetraoxide sulphate | 12065-90-6 | – |
129 | Pentacosafluorotridecanoic acid | 72629-94-8 | – |
130 | Orange lead (lead tetroxide) | 1314-41-6 | – |
131 | o-toluidine | 95-53-4 | – |
132 | o-aminoazotoluene | 97-56-3 | – |
133 | N-methylacetamide | 79-16-3 | – |
134 | N,N-dimethylformamide | 68-12-2 | – |
135 | Methyloxirane (Propylene oxide) | 75-56-9 | – |
136 | Methoxyacetic acid | 625-45-6 | – |
137 | Lead titanium zirconium oxide | 12626-81-2 | – |
138 | Lead titanium trioxide | 12060-00-3 | – |
139 | Lead oxide sulphate | 12036-76-9 | – |
140 | Lead monoxide (lead oxide) | 1317-36-8 | – |
141 | Lead dinitrate | 10099-74-8 | – |
142 | Lead cyanamidate | 20837-86-9 | – |
143 | Lead bis(tetrafluoroborate) | 13814-96-5 | – |
144 | Hexahydro-1-methylphthalic anhydride | 48122-14-1 | – |
145 | Hexahydromethylphthalic anhydride | 25550-51-0 | – |
146 | Hexahydro-4-methylphthalic anhydride | 19438-60-9 | – |
147 | Hexahydro-3-methylphthalic anhydride | 57110-29-9 | – |
148 | Heptacosafluorotetradecanoic acid | 376-06-7 | – |
149 | Henicosafluoroundecanoic acid | 2058-94-8 | – |
150 | Furan | 110-00-9 | – |
151 | Fatty acids, C16-18, lead salts | 91031-62-8 | – |
152 | Dioxobis(stearato)trilead | 12578-12-0 | – |
153 | Dinoseb (6-sec-butyl-2,4-dinitrophenol) | 88-85-7 | – |
154 | Dimethyl sulphate | 77-78-1 | – |
155 | Diisopentyl phthalate | 605-50-5 | – |
156 | Diethyl sulphate | 64-67-5 | – |
157 | Dibutyltin dichloride (DBTC) | 683-18-1 | – |
158 | Diazene-1,2-dicarboxamide (C,C’azodi(formamide)) (ADCA) | 123-77-3 | – |
159 | cis-cyclohexane-1,2-dicarboxylic anhydride | 13149-00-3 | – |
160 | Cyclohexane-1,2-dicarboxylic anhydride | 85-42-7 | – |
161 | trans-cyclohexane-1,2-dicarboxylic anhydride | 14166-21-3 | – |
162 | Bis(pentabromophenyl) ether (decabromodiphenyl ether) (DecaBDE) | 1163-19-5 | – |
163 | Biphenyl-4-ylamine | 92-67-1 | – |
164 | Acetic acid, lead salt, basic | 51404-69-4 | – |
165 | [Phthalato(2-)]dioxotrilead | 69011-06-9 | – |
166 | 6-methoxy-m-toluidine (p-cresidine) | 120-71-8 | – |
167 | 4-(1-ethyl-1-methylhexyl)phenol | 52427-13-1 | – |
168 | p-(1-methyloctyl)phenol | 17404-66-9 | – |
169 | p-(1,1-dimethylheptyl)phenol | 30784-30-6 | – |
170 | 4-(3,6-Dimethyl-3-heptyl)phenol | 142731-63- 3 | – |
171 | Phenol, 4-nonyl-, branched | 84852-15-3 | – |
172 | p-nonylphenol | 104-40-5 | – |
173 | p-isononylphenol | 26543-97-5 | – |
174 | 4-(3,5-Dimethyl-3-heptyl)phenol | 186825-36- 5 | – |
175 | Nonylphenol | 25154-52-3 | – |
176 | 4-(3-ethylheptan-2-yl)phenol | 186825-39- 8 | – |
177 | Phenol, nonyl-, branched | 90481-04-2 | – |
178 | Isononylphenol | 11066-49-2 | – |
179 | 4-(2,6-Dimethyl-2-heptyl)phenol | 521947-27- 3 | – |
180 | 4-methyl-m-phenylenediamine (toluene-2,4diamine) | 95-80-7 | – |
181 | 4-aminoazobenzene | 60-09-3 | – |
182 | 20-[4-(1,1,3,3-tetramethylbutyl)phenoxy]- 3,6,9,12,15,18-hexaoxaicosan-1-ol | 2497-59-8 | – |
183 | 4-tert-Octylphenol monoethoxylate | 2315-67-5 | – |
184 | 2-{2-[4-(2,4,4-trimethylpentan-2yl)phenoxy]ethoxy}ethanol | 2315-61-9 | – |
185 | 2-[4-(2,4,4-trimethylpentan-2-yl)phenoxy]ethanol | 9002-93-1 | – |
186 | 4,4′-oxydianiline | 101-80-4 | – |
187 | 4,4′-methylenedi-o-toluidine | 838-88-0 | – |
188 | 3-ethyl-2-methyl-2-(3-methylbutyl)-1,3oxazolidine | 143860-04- 2 | – |
189 | 1-bromopropane (n-propyl bromide) | 106-94-5 | – |
190 | 1,2-diethoxyethane | 629-14-1 | – |
191 | 1,2-Benzenedicarboxylic acid, dipentyl ester, branched and linear | 84777-06-0 | – |
192 | α,α-Bis[4-(dimethylamino)phenyl]-4 (phenylamino)naphthalene-1-methanol (C.I. Solvent Blue 4) | 6786-83-0 | – |
193 | N,N,N’,N’-tetramethyl-4,4′-methylenedianiline (Michler‘s base) | 101-61-1 | – |
194 | Lead(II) bis(methanesulfonate) | 17570-76-2 | – |
195 | Formamide | 75-12-7 | – |
196 | Diboron trioxide | 1303-86-2 | – |
197 | [4-[[4-anilino-1-naphthyl][4- (dimethylamino)phenyl]methylene]cyclohexa-2,5dien-1-ylidene] dimethylammonium chloride (C.I. Basic Blue 26) | 2580-56-5 | – |
198 | [4-[4,4′-bis(dimethylamino) benzhydrylidene]cyclohexa-2,5-dien-1ylidene]dimethylammonium chloride (C.I. Basic Violet 3) | 548-62-9 | – |
199 | 4,4′-bis(dimethylamino)benzophenone (Michler‘s ketone) | 90-94-8 | – |
200 | 4,4′-bis(dimethylamino)-4”-(methylamino)trityl alcohol | 561-41-1 | – |
201 | 1,3,5-tris[(2S and 2R)-2,3-epoxypropyl]-1,3,5triazine-2,4,6-(1H,3H,5H)-trione (β-TGIC) | 59653-74-6 | – |
202 | 1,3,5-Tris(oxiran-2-ylmethyl)-1,3,5-triazinane- 2,4,6-trione (TGIC) | 2451-62-9 | – |
203 | 1,2-bis(2-methoxyethoxy)ethane (TEGDME; triglyme) | 112-49-2 | – |
204 | 1, 2-dimethoxyethane; ethylene glycol dimethyl ether (EGDME) | 110-71-4 | – |
205 | Trilead diarsenate | 3687-31-8 | – |
206 | Potassium hydroxyoctaoxodizincatedichromate | 11103-86-9 | – |
207 | Phenolphthalein | 77-09-8 | – |
208 | Pentazinc chromate octahydroxide | 49663-84-5 | – |
209 | N,N-dimethylacetamide | 127-19-5 | – |
210 | Lead styphnate | 15245-44-0 | – |
211 | Lead dipicrate | 6477-64-1 | – |
212 | Lead diazide, Lead azide | 13424-46-9 | – |
213 | Formaldehyde, oligomeric reaction products with aniline | 25214-70-4 | – |
214 | Dichromium tris(chromate) | 24613-89-6 | – |
215 | Calcium arsenate | 7778-44-1 | – |
216 | Bis(2-methoxyethyl) phthalate | 117-82-8 | – |
217 | Bis(2-methoxyethyl) ether | 111-96-6 | – |
218 | Arsenic acid | 7778-39-4 | – |
219 | 4-(1,1,3,3-tetramethylbutyl)phenol | 140-66-9 | – |
220 | 2-Methoxyaniline, o-Anisidine | 90-04-0 | – |
221 | 2,2′-dichloro-4,4′-methylenedianiline | 101-14-4 | – |
222 | 1,2-dichloroethane | 107-06-2 | – |
223 | Strontium chromate | 7789-06-2 | – |
224 | Hydrazine | 302-01-2, 7803-57-8 | – |
225 | 2-ethoxyethyl acetate | 111-15-9 | – |
226 | 1-Methyl-2-pyrrolidone (NMP) | 872-50-4 | – |
227 | 1,2-Benzenedicarboxylic acid, di-C7-11-branched and linear alkyl esters | 68515-42-4 | – |
228 | 1,2-Benzenedicarboxylic acid, di-C6-8-branched alkyl esters, C7-rich | 71888-89-6 | – |
229 | 1,2,3-trichloropropane | 96-18-4 | – |
230 | Cobalt(II) sulphate | 10124-43-3 | – |
231 | Cobalt(II) dinitrate | 10141-05-6 | – |
232 | Cobalt(II) diacetate | 71-48-7 | – |
233 | Cobalt(II) carbonate | 513-79-1 | – |
234 | Chromium trioxide | 1333-82-0 | – |
235 | Dichromic acid | 13530-68-2 | – |
236 | Chromic acid | 7738-94-5 | – |
237 | 2-methoxyethanol | 109-86-4 | – |
238 | 2-ethoxyethanol | 110-80-5 | – |
239 | Trichloroethylene | 79-01-6 | – |
240 | Tetraboron disodium heptaoxide, hydrate | 12267-73-1 | – |
241 | Sodium chromate | 7775-11-3 | – |
242 | Potassium dichromate | 7778-50-9 | – |
243 | Potassium chromate | 7789-00-6 | – |
244 | Disodium tetraborate, anhydrous | 12179-04-3, 1303-96-4, 1330-43-4 | – |
245 | Boric acid, crude natural | 11113-50-1 | – |
246 | Boric acid | 10043-35-3 | – |
247 | Ammonium dichromate | 7789-09-5 | – |
248 | Acrylamide | 79-06-1 | – |
249 | Tris(2-chloroethyl) phosphate | 115-96-8 | – |
250 | Pitch, coal tar, high-temp. | 65996-93-2 | – |
251 | Lead sulfochromate yellow (C.I. Pigment Yellow 34) | 1344-37-2 | – |
252 | Lead chromate molybdate sulphate red (C.I. Pigment Red 104) | 12656-85-8 | – |
253 | Lead chromate | 7758-97-6 | – |
254 | Diisobutyl phthalate | 84-69-5 | – |
255 | Anthracene oil, anthracene-low | 90640-82-7 | – |
256 | Anthracene oil, anthracene paste, distn. lights | 91995-17-4 | – |
257 | Anthracene oil, anthracene paste, anthracene fraction | 91995-15-2 | – |
258 | Anthracene oil, anthracene paste | 90640-81-6 | – |
259 | Anthracene oil | 90640-80-5 | – |
260 | 2,4-dinitrotoluene | 121-14-2 | – |
261 | Triethyl arsenate | 15606-95-8 | – |
262 | Sodium dichromate | 10588-01-9, 7789-12-0 | – |
263 | Lead hydrogen arsenate | 7784-40-9 | – |
264 | 1,2,5,6,9,10-hexabromocyclododecane | 3194-55-6 | – |
265 | gamma-hexabromocyclododecane | 134237-52- 8 | – |
266 | Hexabromocyclododecane | 25637-99-4 | – |
267 | alpha-hexabromocyclododecane | 134237-50- 6 | – |
268 | beta-hexabromocyclododecane | 134237-51- 7 | – |
269 | Dibutyl phthalate (DBP) | 84-74-2 | – |
270 | Diarsenic trioxide | 1327-53-3 | – |
271 | Diarsenic pentaoxide | 1303-28-2 | – |
272 | Cobalt dichloride | 7646-79-9 | – |
273 | Bis(tributyltin) oxide (TBTO) | 56-35-9 | – |
274 | Bis (2-ethylhexyl)phthalate (DEHP) | 117-81-7 | – |
275 | Benzyl butyl phthalate (BBP) | 85-68-7 | – |
276 | Anthracene | 120-12-7 | – |
277 | Alkanes, C10-13, chloro (Short Chain Chlorinated Paraffins) | 85535-84-8 | – |
278 | 5-tert-butyl-2,4,6-trinitro-m-xylene (Musk xylene) | 81-15-2 | – |
279 | 4,4′- Diaminodiphenylmethane (MDA) | 101-77-9 | – |
280 | 1,1,1,2-Tetrachloroethane | 630-20-6 | – |
281 | 1,1,2,2-Tetrachloroethane | 79-34-5 | – |
282 | 1,1,2-Trichloroethane | 79-00-5 | – |
283 | 1,1-Dichloroethene | 75-35-4 | – |
284 | 1,4-Dichlorobenzene | 106-46-7 | – |
285 | 1-methyl-2-pyrrolidone | 872-50-4 | – |
286 | 2-(2-butoxyethoxy)ethanol (DEGBE) | 112-34-5 | – |
287 | 2-(2-methoxyethoxy)ethanol (DEGME) | 111-77-3 | – |
288 | 2-naphthylamine | 91-59-8 | – |
289 | 2-naphthylammonium chloride | 612-52-2 | – |
290 | 2-naphthylammonium acetate | 553-00-4 | – |
291 | 4,4′-isopropylidenediphenol | 80-05-7 | – |
292 | 4-Aminobiphenyl xenylamine | 92-67-1 | – |
293 | 4-Nitrobiphenyl | 92-93-3 | – |
294 | Acrylamide | 79-06-1 | – |
295 | Ammonium nitrate (AN) | 6484-52-2 | – |
296 | Trisodium arsenide | 12044-25-6 | – |
297 | Praseodymium arsenide | 12044-28-9 | – |
298 | Trimagnesium diarsenide | 12044-49-4 | – |
299 | Diarsenic tritelluride | 12044-54-1 | – |
300 | Zinc diarsenide | 12044-55-2 | – |
301 | Nickel diarsenide | 12068-61-0 | – |
302 | Dichromium arsenide | 12254-85-2 | – |
303 | Erbium arsenide | 12254-88-5 | – |
304 | Lanthanum arsenide | 12255-04-8 | – |
305 | Niobium arsenide | 12255-08-2 | – |
306 | Neodymium arsenide | 12255-09-3 | – |
307 | Triantimony arsenide | 12255-36-6 | – |
308 | Samarium arsenide | 12255-39-9 | – |
309 | Yttrium arsenide | 12255-48-0 | – |
310 | Tribarium diarsenide | 12255-50-4 | – |
311 | Tricalcium diarsenide | 12255-53-7 | – |
312 | Germanium arsenide | 12271-72-6 | – |
313 | Trisilver arsenide | 12417-99-1 | – |
314 | Arsenic sulphide | 12612-21-4 | – |
315 | Ammonium dihydrogenarsenate | 13462-93-6 | – |
316 | Potassium arsenite | 13464-35-2 | – |
317 | Trisodium arsenite | 13464-37-4 | – |
318 | Trisodium arsenate | 13464-38-5 | – |
319 | Zinc arsenate | 13464-44-3 | – |
320 | Tristrontium diarsenate | 13464-68-1 | – |
321 | Tribarium diarsenate | 13477-04-8 | – |
322 | Trinickel bis(arsenate) | 13477-70-8 | – |
323 | Trilithium arsenate | 13478-14-3 | – |
324 | Trisilver arsenate | 13510-44-6 | – |
325 | Sodium metaarsenate | 15120-17-9 | – |
326 | Triethyl arsenite | 3141-12-6 | – |
327 | Trilead diarsenate | 3687-31-8 | – |
328 | Disodium 4-[(o-arsonophenyl)azo]-3hydroxynaphthalene-2,7-disulphonate | 3688-92-4 | – |
329 | Diphenyldiarsenic acid | 4519-32-8 | – |
330 | Dimethylarsinic acid | 75-60-5 | – |
331 | Roxarsone | 121-19-7 | – |
332 | Sodium dimethylarsinate | 124-65-2 | – |
333 | 6,6′-dihydroxy-3,3′-diarsene-1,2-diyldianilinium dichloride | 139-93-5 | – |
334 | Oxophenarsine | 306-12-7 | – |
335 | Copper diarsenite | 16509-22-1 | – |
336 | Potassium hexafluoroarsenate | 17029-22-0 | – |
337 | Hydrogen hexafluoroarsenate | 17068-85-8 | – |
338 | N-(p-arsenosophenyl)-1,3,5-triazine-2,4,6triamine | 21840-08-4 | – |
339 | Aluminium arsenide | 22831-42-1 | – |
340 | Triammonium arsenate | 24719-13-9 | – |
341 | Tricobalt diarsenate | 24719-19-5 | – |
342 | Cobalt arsenide | 27016-73-5 | – |
343 | Nickel arsenide | 27016-75-7 | – |
344 | Tricalcium diarsenite | 27152-57-4 | – |
345 | 3-methyl-4-(pyrrolidin-1-yl)benzenediazonium hexafluoroarsenate | 27569-09-1 | – |
346 | Antimony arsenate | 28980-47-4 | – |
347 | Arsenic acid, copper(2+) salt | 29871-13-4 | – |
348 | Lithium hexafluoroarsenate | 29935-35-1 | – |
349 | Ammonium copper arsenate | 32680-29-8 | – |
350 | Europium arsenide | 32775-46-5 | – |
351 | Tristrontium diarsenide | 39297-24-0 | – |
352 | Triphenylsulphonium hexafluoroarsenate(1-) | 57900-42-2 | – |
353 | Zirconium arsenide | 60909-47-9 | – |
354 | Trimanganese arsenide | 61219-26-9 | – |
355 | Disodium 3,6-bis[(o-arsonophenyl)azo]-4,5dihydroxynaphthalene-2,7-disulphonate | 62337-00-2 | – |
356 | Diphenyliodonium hexafluoroarsenate | 62613-15-4 | – |
357 | 4-(ethylamino)-2-methylbenzenediazonium hexafluoroarsenate | 63217-32-3 | – |
358 | 4-(diethylamino)-2-ethoxybenzenediazonium hexafluoroarsenate | 63217-33-4 | – |
359 | Antimony arsenic oxide | 64475-90-7 | – |
360 | Arsenic bromide | 64973-06-4 | – |
361 | Cobalt arsenide | 65453-05-6 | – |
362 | Tris(pentane-2,4-dionato-O,O’)silicon hexafluoroarsenate | 67251-38-1 | – |
363 | Slimes and Sludges, copper refining | 67712-00-9 | – |
364 | Silicic acid (H4SiO4), zinc salt (1:2), arsenic and manganese-doped | 68611-46-1 | – |
365 | Bis(pentane-2,4-dionato-O,O’)boron(1+) hexafluoroarsenate(1-) | 68892-01-3 | – |
366 | Antimony oxide (Sb2O3), mixed with arsenic oxide (As2O3) | 68951-38-2 | – |
367 | Lead alloy, base, dross | 69011-59-2 | – |
368 | Lead, antimonial, dross | 69029-51-2 | – |
369 | Flue dust, lead-refining | 69029-67-0 | – |
370 | Disilver arsenide | 70333-07-2 | – |
371 | Thallium triarsenide | 84057-85-2 | – |
372 | 2,6-dimethyl-4-(1-naphthyl)pyrylium hexafluoroarsenate | 84282-36-0 | – |
373 | 2,6-dimethyl-4-phenylpyrylium hexafluoroarsenate | 84304-15-4 | – |
374 | 4-cyclohexyl-2,6-dimethylpyrylium hexafluoroarsenate | 84304-16-5 | – |
375 | Tris[(8α)-6′-methoxycinchonan-9(R)-ol] arsenite | 94138-87-1 | – |
376 | Gallium zinc triarsenide | 98106-56-0 | – |
377 | Vanadium(4+) diarsenate (1:1) | 99035-51-5 | – |
378 | Strychnidin-10-one, arsenite (1:1) | 100258-44- 4 | – |
379 | Slimes and Sludges, copper electrolytic refining, decopperized, arsenic-rich | 100995-81- 1 | – |
380 | Arsenic acid (H3AsO4), magnesium salt, manganese-doped | 102110-21- 4 | – |
381 | Slimes and Sludges, copper-lead ore roasting off gas scrubbing, arsenic-contg. | 102110-62- 3 | – |
382 | Sodium hexafluoroarsenate(V) | 12005-86-6 | – |
383 | Sodium arsenate dibasic heptahydrate | 10048-95-0 | – |
384 | Sodium cacodylate trihydrate | 6131-99-3 | – |
385 | Tritylium hexafluoroarsenate | 437-15-0 | – |
386 | Neoarsphenamine | 457-60-3 | – |
387 | Oxophenarsine hydrochloride | 538-03-4 | – |
388 | Tris[(8α,9R)-6′-methoxycinchonan-9-ol] bis(arsenate) | 549-59-7 | – |
389 | Sulfarsphenamine | 618-82-6 | – |
390 | Phenylarsine oxide | 637-03-6 | – |
391 | Gallium arsenide | 1303-00-0 | – |
392 | Indium arsenide | 1303-11-3 | – |
393 | Diarsenic pentaoxide | 1303-28-2 | – |
394 | Arsenic sulphide | 1303-33-9 | – |
395 | Diarsenic triselenide | 1303-36-2 | – |
396 | Diarsenic trioxide | 1327-53-3 | – |
397 | Arsenic | 7440-38-2 | – |
398 | Arsenic acid, sodium salt | 7631-89-2 | – |
399 | Arsenic acid | 7778-39-4 | – |
400 | Disodium hydrogenarsenate | 7778-43-0 | – |
401 | Calcium arsenate | 7778-44-1 | – |
402 | Trisilver arsenite | 7784-08-9 | – |
403 | Arsenic tribromide | 7784-33-0 | – |
404 | Arsenic trichloride | 7784-34-1 | – |
405 | Trifluoroarsine | 7784-35-2 | – |
406 | Pentafluoroarsorane | 7784-36-3 | – |
407 | Mercury hydrogenarsenate | 7784-37-4 | – |
408 | Manganese hydrogenarsenate | 7784-38-5 | – |
409 | Lead hydrogen arsenate | 7784-40-9 | – |
410 | Potassium dihydrogenarsenate | 7784-41-0 | – |
411 | Diammonium hydrogenarsenate | 7784-44-3 | – |
412 | Arsenic triiodide | 7784-45-4 | – |
413 | Sodium dioxoarsenate | 7784-46-5 | – |
414 | Pentahydroxyarsorane | 7786-36-9 | – |
415 | Flue dust, arsenic-contg. | 8028-73-7 | – |
416 | Lead arsenite | 10031-13-7 | – |
417 | Iron arsenate | 10102-49-5 | – |
418 | Iron bis(arsenate) | 10102-50-8 | – |
419 | Arsenic acid, magnesium salt | 10103-50-1 | – |
420 | Arsenic acid, copper salt | 10103-61-4 | – |
421 | Arsenic acid, calcium salt | 10103-62-5 | – |
422 | Strychnine arsenate | 10476-82-1 | – |
423 | Tricopper arsenide | 12005-75-3 | – |
424 | Dysprosium arsenide | 12005-81-1 | – |
425 | Diiron arsenide | 12005-88-8 | – |
426 | Gadolinium arsenide | 12005-89-9 | – |
427 | Holmium arsenide | 12005-92-4 | – |
428 | Lutetium arsenide | 12005-94-6 | – |
429 | Manganese arsenide | 12005-95-7 | – |
430 | Terbium arsenide | 12006-08-5 | – |
431 | Thallium arsenide | 12006-09-6 | – |
432 | Thulium arsenide | 12006-10-9 | – |
433 | Ytterbium arsenide | 12006-12-1 | – |
434 | Iron diarsenide | 12006-21-2 | – |
435 | Trizinc diarsenide | 12006-40-5 | – |
436 | Iron arsenide | 12044-16-5 | – |
437 | Digallium arsenide phosphide | 12044-20-1 | – |
438 | Tripotassium arsenide | 12044-21-2 | – |
439 | Trilithium arsenide | 12044-22-3 | – |
440 | Actinolite | 77536-66-4 | – |
441 | Tremolite | 77536-68-6 | – |
442 | Crocidolite | 12001-28-4 | – |
443 | Amosite | 12172-73-5 | – |
444 | Chrysotile | 12001-29-5, 132207-32- 0 | – |
445 | Anthophyllite | 77536-67-5 | – |
446 | A mixture of: disodium (6-(4-anisidino)-3sulfonato-2-(3,5-dinitro-2-oxidophenylazo)-1naphtholato)(1-(5-chloro-2-oxidophenylazo)-2naphtholato)chromate(1-); trisodium bis(6-(4anisidino)-3-sulfonato-2-(3,5-dinitro-2oxidophenylazo)-1-naphtholato)chromate(1-) | 118685-33- 9 | – |
447 | Benzene | 71-43-2 | – |
448 | Benzidine | 92-87-5 | – |
449 | Bis(pentabromophenyl) ether | 1163-19-5 | – |
450 | Cadmium succinate | 141-00-4 | – |
451 | Cadmium dianthranilate | 7058-55-1 | – |
452 | Cadmium | 7440-43-9 | – |
453 | Cadmium bromide | 7789-42-6 | – |
454 | Cadmium fluoride | 7790-79-6 | – |
455 | Cadmium iodide | 7790-80-9 | – |
456 | Cadmium iodate | 7790-81-0 | – |
457 | Cadmium dinitrite | 7790-83-2 | – |
458 | Cadmium wolframate | 7790-85-4 | – |
459 | Cadmium zinc sulfide yellow | 8048-07-5 | – |
460 | Cadmium chloride | 10108-64-2 | – |
461 | Cadmium sulphate | 10124-36-4 | – |
462 | Cadmium myristate | 10196-67-5 | – |
463 | Cadmium nitrate | 10325-94-7 | – |
464 | Cadmium dioleate | 10468-30-1 | – |
465 | Cadmium selenide sulphide | 11112-63-3 | – |
466 | Cadmium titanium trioxide | 12014-14-1 | – |
467 | Tricadmium diphosphide | 12014-28-7 | – |
468 | Antimony, compound with cadmium (2:3) | 12014-29-8 | – |
469 | Cadmium zirconium trioxide | 12139-23-0 | – |
470 | Pentacadmium chloridetriphosphate | 12185-64-7 | – |
471 | Dicadmium niobate | 12187-14-3 | – |
472 | Dicadmium selenide sulphide | 12214-12-9 | – |
473 | Cadmium ditantalum hexaoxide | 12292-07-8 | – |
474 | Cadmium zinc sulphide | 12442-27-2 | – |
475 | Cadmium selenide sulphide | 12626-36-7 | – |
476 | Cadmium sulfoselenide orange | 12656-57-4 | – |
477 | Tricadmium bis(phosphate) | 13477-17-3 | – |
478 | Cadmium silicate | 13477-19-5 | – |
479 | Cadmium sulphite | 13477-23-1 | – |
480 | Diboron tricadmium hexaoxide | 13701-66-1 | – |
481 | Dicadmium hexakis(cyano-C)ferrate(4-) | 13755-33-4 | – |
482 | Cadmium selenite | 13814-59-0 | – |
483 | Cadmium selenite | 13814-62-5 | – |
484 | Cadmium diricinoleate | 13832-25-2 | – |
485 | Cadmium orthophosphate | 13847-17-1 | – |
486 | Cadmium molybdenum tetroxide | 13972-68-4 | – |
487 | Cadmium disulphamate | 14017-36-8 | – |
488 | Cadmium hydrogen phosphate | 14067-62-0 | – |
489 | Cadmium bis(diethyldithiocarbamate) | 14239-68-0 | – |
490 | Cadmium chromate | 14312-00-6 | – |
491 | Cadmium dipotassium tetracyanide | 14402-75-6 | – |
492 | Cadmium tetrafluoroborate | 14486-19-2 | – |
493 | Bis(dibutyldithiocarbamato-S,S’)cadmium | 14566-86-0 | – |
494 | Bis(pentane-2,4-dionato-O,O’)cadmium | 14689-45-3 | – |
495 | Tris(ethylenediamine)cadmium dihydroxide | 14874-24-9 | – |
496 | Cadmium diicosanoate | 14923-81-0 | – |
497 | Cadmium bis(piperidine-1-carbodithioate) | 14949-59-8 | – |
498 | Bis(dimethyldithiocarbamato-S,S’)cadmium | 14949-60-1 | – |
499 | Dimethylcadmium | 506-82-1 | – |
500 | Cadmium carbonate | 513-78-0 | – |
501 | Cadmium cyanide | 542-83-6 | – |
502 | Cadmium di(acetate) | 543-90-8 | – |
503 | Cadmium oxalate | 814-88-0 | – |
504 | Cadmium dithiocyanate | 865-38-3 | – |
505 | Barium cadmium tetrastearate | 1191-79-3 | – |
506 | Cadmium oxide | 1306-19-0 | – |
507 | Cadmium sulphide | 1306-23-6 | – |
508 | Cadmium selenide | 1306-24-7 | – |
509 | Cadmium telluride | 1306-25-8 | – |
510 | Cadmium di(octanoate) | 2191-10-8 | – |
511 | Cadmium distearate | 2223-93-0 | – |
512 | Cadmium p-toluate | 2420-97-5 | – |
513 | Cadmium bis(2-ethylhexanoate) | 2420-98-6 | – |
514 | Cadmium dilaurate | 2605-44-9 | – |
515 | Cadmium didecanoate | 2847-16-7 | – |
516 | Cadmium bis[benzoate] | 3026-22-0 | – |
517 | Cadmium 4-(1,1-dimethylethyl)benzoate | 4167-05-9 | – |
518 | Cadmium cinnamate | 4390-97-0 | – |
519 | Cadmium diformate | 4464-23-7 | – |
520 | Cadmium sebacate | 4476-04-4 | – |
521 | Cadmium nonan-1-oate | 5112-16-3 | – |
522 | Cadmium dipalmitate | 6427-86-7 | – |
523 | Lauric acid, barium cadmium salt | 15337-60-7 | – |
524 | Disodium tetrakis(cyano-C)cadmate(2-) | 15682-87-8 | – |
525 | Dipotassium [[N,N’-ethylenebis[N- (carboxymethyl)glycinato]](4-)N,N’,O,O’,ON,ON’]cadmate(2-) | 15708-29-9 | – |
526 | Cadmium acrylate | 15743-19-8 | – |
527 | Cadmium tellurium trioxide | 15851-44-2 | – |
528 | Cadmium tellurium tetraoxide | 15852-14-9 | – |
529 | Cadmium dilactate | 16039-55-7 | – |
530 | Cadmium divanadium hexoxide | 16056-72-7 | – |
531 | 5-oxo-L-proline, cadmium salt | 16105-06-9 | – |
532 | Cadmium propionate | 16986-83-7 | – |
533 | Cadmium hexafluorosilicate(2-) | 17010-21-8 | – |
534 | Bis(ethylenediamine)cadmium(2+) bis[dicyanoaurate(1-)] | 18974-20-4 | – |
535 | Cadmium diphenolate | 18991-05-4 | – |
536 | Cadmium bis(dipentyldithiocarbamate) | 19010-65-2 | – |
537 | Cadmium disalicylate | 19010-79-8 | – |
538 | Cadmium hydroxide | 21041-95-2 | – |
539 | Cadmium methacrylate | 24345-60-6 | – |
540 | Cadmium epoxyoctadecanoate | 26264-48-2 | – |
541 | Cadmium toluate | 27476-27-3 | – |
542 | [[N,N’-ethylenebis[glycinato]](2-)- N,N’,O,O’]cadmium | 29977-13-7 | – |
543 | Cadmium isooctanoate | 30304-32-6 | – |
544 | Cadmium dodecylbenzenesulphonate | 31017-44-4 | – |
545 | Cadmium (1,1-dimethylethyl)benzoate | 31215-94-8 | – |
546 | Cadmium [R-(R*,R*)]-tartrate | 34100-40-8 | – |
547 | Cadmium didocosanoate | 34303-23-6 | – |
548 | Cadmium 3,5,5-trimethylhexanoate | 36211-44-6 | – |
549 | Cadmium(2+) (R)-12-hydroxyoctadecanoate | 38517-19-0 | – |
550 | Potassium [N,N-bis(carboxymethyl)glycinato(3-)- N,O,O’,O”]cadmate(1-) | 49784-42-1 | – |
551 | Bis[N,N-bis(carboxymethyl)glycinato(3- )]tricadmium | 50648-02-7 | – |
552 | Boric acid, cadmium salt | 51222-60-7 | – |
553 | Cadmium o-toluate | 52337-78-7 | – |
554 | Cadmium bis(4-cyclohexylbutyrate) | 55700-14-6 | – |
555 | Cadmium divalerate | 56982-42-4 | – |
556 | Cadmium sulfoselenide red | 58339-34-7 | – |
557 | Naphthenic acids, cadmium salts | 61789-34-2 | – |
558 | Cadmium neodecanoate | 61951-96-0 | – |
559 | Cadmium bis(heptadecanoate) | 62149-56-8 | – |
560 | Cadmium pentadecanoate | 63400-09-9 | – |
561 | (S)-dichloro[2-[[(2,3dihydroxypropoxy)hydroxyphosphinyl]oxy]triethy lmethylammoniumato]cadmium | 64681-08-9 | – |
562 | Bis(propane-1,2-diyldiamine-N,N’)cadmium(2+) bis[bis(cyano-C)aurate(1-)] | 67906-19-8 | – |
563 | Cadmium dilinoleate | 67939-62-2 | – |
564 | Tetrapotassium [[[nitrilotris(methylene)]tris[phosphonato]](6-)- N,O,O”,O””]cadmate(6-) | 67989-93-9 | – |
565 | Cadmium m-toluate | 68092-45-5 | – |
566 | Fatty acids, C10-18, cadmium salts | 68131-58-8 | – |
567 | Fatty acids, C12-18, cadmium salts | 68131-59-9 | – |
568 | Benzyltriphenylphosphonium tetrachlorocadmate | 68214-25-5 | – |
569 | Pentapotassium hydrogen [[[ethylenebis[nitrilobis(methylene)]]tetrakis[phos phonato]](8-)]cadmate(6-) | 68309-98-8 | – |
570 | Cadmium sulfide (CdS), solid soln. with zinc sulfide, copper and lead-doped | 68332-81-0 | – |
571 | Fatty acids, C14-18, cadmium salts | 68409-82-5 | – |
572 | Cadmium, benzoate p-tert-butylbenzoate complexes | 68478-53-5 | – |
573 | Pyrochlore, bismuth cadmium ruthenium | 68479-13-0 | – |
574 | Cadmium sulfide (CdS), solid soln. with zinc sulfide, aluminum and cobalt and copper and silver-doped | 68784-10-1 | – |
575 | Barium cadmium calcium chloride fluoride phosphate, antimony and manganese-doped | 68784-55-4 | – |
576 | Fatty acids, tall-oil, cadmium salts | 68855-80-1 | – |
577 | Fatty acids, C8-18 and C18-unsatd., cadmium salts | 68876-84-6 | – |
578 | Cadmium sulfide (CdS), aluminum and copperdoped | 68876-98-2 | – |
579 | Cadmium sulfide (CdS), aluminum and silverdoped | 68876-99-3 | – |
580 | Cadmium sulfide (CdS), copper chloride-doped | 68877-00-9 | – |
581 | Cadmium sulfide (CdS), silver chloride-doped | 68877-01-0 | – |
582 | Cadmium sulfide (CdS), copper and lead-doped | 68891-87-2 | – |
583 | Fatty acids, tallow, hydrogenated, cadmium salts | 68953-39-9 | – |
584 | Resin acids and Rosin acids, cadmium salts | 68956-81-0 | – |
585 | Hydrogen [4-[(5-chloro-4-methyl-2sulphophenyl)azo]-3-hydroxynaphthalene-2carboxylato(3-)]cadmate(1-) | 68966-97-2 | – |
586 | Cadmium, dross | 69011-69-4 | – |
587 | Wastewater, cadmium sulfate electrolytic, acid | 69012-21-1 | – |
588 | Flue dust, cadmium-refining | 69012-57-3 | – |
589 | Calcines, cadmium residue | 69029-63-6 | – |
590 | Leach residues, cadmium-refining | 69029-70-5 | – |
591 | Residues, cadmium-refining | 69029-77-2 | – |
592 | Slimes and Sludges, cadmium-refining, oxidized | 69029-90-9 | – |
593 | Slimes and Sludges, cadmium sump tank | 69029-91-0 | – |
594 | Cadmium(2+) 12-hydroxyoctadecanoate | 69121-20-6 | – |
595 | Cadmium potassium 1- (hydroxyethylidene)bisphosphonate(1:2:1) | 69190-99-4 | – |
596 | Fatty acids, C12-18, barium cadmium salts | 70084-75-2 | – |
597 | Cadmium selenide (CdSe), solid soln. with cadmium sulphide | 71243-75-9 | – |
598 | (R)-12-hydroxyoleic acid, barium cadmium salt | 71411-66-0 | – |
599 | Tetra-μ-chlorodichlorobis[2-[[(2,3dihydroxypropoxy)hydroxyphosphinyl]oxy]triethy lmethylammoniumato]tricadmium, stereoisomer | 71861-27-3 | – |
600 | Fatty acids, coco, cadmium salts | 72869-63-7 | – |
601 | Zircon, cadmium yellow | 72968-34-4 | – |
602 | Cadmium isononanoate | 84696-56-0 | – |
603 | Cadmium isooctadecanoate | 84878-36-4 | – |
604 | Cadmium tert-decanoate | 84878-37-5 | – |
605 | Cadmium bis(nonylphenolate) | 84878-48-8 | – |
606 | Cadmium bis(octylphenolate) | 84878-51-3 | – |
607 | Flue dust, lead-manufg., cadmium-rich | 85117-02-8 | – |
608 | Waste solids, cadmium-electrolysis, thallium-rich | 85117-20-0 | – |
609 | Fatty acids, C9-11-branched, cadmium salts | 85586-15-8 | – |
610 | Bis(5-oxo-L-prolinato-N1,O2)cadmium | 85958-86-7 | – |
611 | Bis(5-oxo-DL-prolinato-N1,O2)cadmium | 85994-31-6 | – |
612 | Benzenesulfonic acid, mono-C10-13-alkyl derivs., cadmium salts | 90194-35-7 | – |
613 | Benzoic acid, cadmium salt, basic | 90218-85-2 | – |
614 | Decanoic acid, branched, cadmium salts | 90342-19-1 | – |
615 | Hexanoic acid, 2-ethyl-, cadmium salt, basic | 90411-62-4 | – |
616 | Propanoic acid, cadmium salt, basic | 90529-78-5 | – |
617 | Cadmium zinc lithopone yellow | 90604-89-0 | – |
618 | Cadmium lithopone yellow | 90604-90-3 | – |
619 | Leach residues, cadmium cake | 91053-44-0 | – |
620 | Leach residues, zinc ore-calcine, cadmium-copper ppt. | 91053-46-2 | – |
621 | Fatty acids, castor-oil, hydrogenated, cadmium salts | 91697-35-7 | – |
622 | Fatty acids, C8-10-branched, cadmium salts | 92257-06-2 | – |
623 | Leach residues, zinc refining flue dust, cadmiumthallium ppt. | 92257-11-9 | – |
624 | Fatty acids, C9-13-neo-, cadmium salts | 92704-12-6 | – |
625 | Fatty acids, olive-oil, cadmium salts | 92704-15-9 | – |
626 | Fatty acids, peanut-oil, cadmium salts | 92704-19-3 | – |
627 | Fatty acids, rape-oil, cadmium salts | 92704-24-0 | – |
628 | Fatty acids, C14-18 and C18-unsatd., branched and linear, hydrogenated, cadmium salts | 92797-28-9 | – |
629 | Nonanoic acid, branched, cadmium salt | 93686-40-9 | – |
630 | Carbonic acid, cadmium salt | 93820-02-1 | – |
631 | Bis(2-ethylhexyl mercaptoacetato -O’,S)cadmium | 93858-50-5 | – |
632 | Cadmium bis(o-nonylphenolate) | 93894-07-6 | – |
633 | Cadmium bis(p-nonylphenolate) | 93894-08-7 | – |
634 | Cadmium bis[p-(1,1,3,3tetramethylbutyl)phenolate] | 93894-09-8 | – |
635 | Cadmium (Z)-hexadec-9-enoate | 93894-10-1 | – |
636 | Cadmium isodecanoate | 93965-24-3 | – |
637 | Cadmium bis(isoundecanoate) | 93965-30-1 | – |
638 | Cadmium dimethylhexanoate | 93983-65-4 | – |
639 | Cadmium tetrapentyl bis(phosphate) | 94232-49-2 | – |
640 | Cadmium isooctyl phthalate (1:2:2) | 94247-16-2 | – |
641 | Cadmium (1-ethylhexyl) phthalate (1:2:2) | 94275-93-1 | – |
642 | Cadmium octyl phthalate (1:2:2) | 94275-94-2 | – |
643 | Leach residues, cadmium-contg. flue dust | 94551-70-9 | – |
644 | Cadmium isohexadecanoate | 95892-12-9 | – |
645 | Cadmium diisobutyl dimaleate | 97259-82-0 | – |
646 | Zircon, cadmium orange | 99749-34-5 | – |
647 | Cadmium chloride phosphate (Cd5Cl(PO4)3), manganese-doped | 100402-53- 7 | – |
648 | Flue dust, copper-lead blast furnace, cadmiumindium-enriched | 100656-55- 1 | – |
649 | Dodecanoic acid, cadmium salt, basic | 101012-89- 9 | – |
650 | Octadecanoic acid, cadmium salt, basic | 101012-93- 5 | – |
651 | Octadecanoic acid, 12-hydroxy-, cadmium salt, basic | 101012-94- 6 | – |
652 | Cadmium oxide (CdO), solid soln. with calcium oxide and titanium oxide (TiO2), praseodymiumdoped | 101356-99- 4 | – |
653 | Cadmium selenide (CdSe), solid soln. with cadmium sulfide, zinc selenide and zinc sulfide, aluminum and copper-doped | 101357-00- 0 | – |
654 | Cadmium selenide (CdSe), solid soln. with cadmium sulfide, zinc selenide and zinc sulfide, copper and manganese-doped | 101357-01- 1 | – |
655 | Cadmium selenide (CdSe), solid soln. with cadmium sulfide, zinc selenide and zinc sulfide, europium-doped | 101357-02- 2 | – |
656 | Cadmium selenide (CdSe), solid soln. with cadmium sulfide, zinc selenide and zinc sulfide, gold and manganese-doped | 101357-03- 3 | – |
657 | Cadmium selenide (CdSe), solid soln. with cadmium sulfide, zinc selenide and zinc sulfide, manganese and silver-doped | 101357-04- 4 | – |
658 | Cadmium oxide (CdO), solid soln. with magnesium oxide, tungsten oxide (WO3) and zinc oxide | 102110-30- 5 | – |
659 | Silicic acid, zirconium salt, cadmium pigmentencapsulated | 102184-95- 2 | – |
660 | Cadmium Acetate, Dihydrate | 5743-04-4 | – |
661 | cadmium sulphate hydrate (3:8) | 7790-84-3 | – |
662 | Cadmium (II) chloride monohydrate | 35658-65-2 | – |
663 | Cadmium perchlorate hexahydrate | 10326-28-0 | – |
664 | Cadmium chloride hydrate | 654054-66- 7 | – |
665 | cadmium chloride, hydrate(2:5) | 7790-78-5 | – |
666 | Chloroethene | 75-01-4 | – |
667 | Chloroform | 67-66-3 | – |
668 | Cyclohexane | 110-82-7 | – |
669 | Di-μ-oxo-di-n-butylstanniohydroxyborane / Dibutyltin hydrogen borate C8H19BO3Sn (DBB) | 75113-37-0 | – |
670 | Dichloromethane | 75-09-2 | – |
671 | Diisobutyl phthalate | 84-69-5 | – |
672 | Bis (2-ethylhexyl) phthalate (DEHP) | 117-81-7 | – |
673 | Benzyl butyl phthalate (BBP) | 85-68-7 | – |
674 | Dibutyl phthalate (DBP) | 84-74-2 | – |
675 | Dimethyl fumarate (DMFu) | 624-49-7 | – |
676 | Ammonium polysulphide | 9080-17-5 | – |
677 | Ammonium sulphide | 12135-76-1 | – |
678 | Ammonium hydrogen sulphide | 12124-99-1 | – |
679 | Creosote oil; wash oil | 61789-28-4 | – |
680 | Tar acids, coal, crude; crude phenols | 65996-85-2 | – |
681 | Distillates (coal tar), upper; heavy anthracene oil | 65996-91-0 | – |
682 | Distillates (coal tar), naphthalene oils; naphthalene oil | 84650-04-4 | – |
683 | Creosote, wood | 8021-39-4 | – |
684 | Creosote oil, acenaphthene fraction; wash oil | 90640-84-9 | – |
685 | Low temperature tar oil, alkaline; extract residues (coal), low temperature coal tar alkaline | 122384-78- 5 | – |
686 | Creosote; wash oil | 8001-58-9 | – |
687 | Anthracene oil | 90640-80-5 | – |
688 | Nonylphenol C6H4(OH)C9H19 | 25154-52-3 | – |
689 | Phenylmercury 2-ethylhexanoate | 13302-00-6 | – |
690 | Phenylmercury neodecanoate | 26545-49-3 | – |
691 | Phenylmercury propionate | 103-27-5 | – |
692 | Phenylmercury acetate | 62-38-4 | – |
693 | Phenylmercury octanoate | 13864-38-5 | – |
694 | o-Nitrobenzaldehyde | 552-89-6 | – |
695 | Soap bark powder (Quillaja saponaria) and its derivatives containing saponines | 68990-67-0 | – |
696 | Hexachloroethane | 67-72-1 | – |
697 | Lead | 7439-92-1 | – |
698 | Trilead-bis(carbonate)-dihydroxide 2PbCO3- Pb(OH)2 | 1319-46-6 | – |
699 | Neutral anhydrous carbonate (PbCO3 ) | 598-63-0 | – |
700 | Lead sulphate PbSO4 | 7446-14-2 | – |
701 | Sulphuric acid, lead salt Pbx SO4 | 15739-80-7 | – |
702 | Mercury | 7439-97-6 | – |
703 | Methanol | 67-56-1 | – |
704 | 4,4‘-Methylenediphenyl diisocyanate | 101-68-8 | – |
705 | Methylenediphenyl diisocyanate (MDI) | 26447-40-5 | – |
706 | 2,4‘-Methylenediphenyl diisocyanate | 5873-54-1 | – |
707 | 2,2‘-Methylenediphenyl diisocyanate | 2536-05-2 | – |
708 | Monomethyl — tetrachlorodiphenyl methane Trade name: Ugilec 141 | 76253-60-6 | – |
709 | Monomethyl-dibromo-diphenyl methane bromobenzylbromotoluene, mixture of isomers Trade name: DBBT | 99688-47-8 | – |
710 | Nickel | 7440-02-0 | – |
711 | Nonylphenol, ethoxylated | 9016-45-9 | – |
712 | 4-Nonylphenol, ethoxylated | 26027-38-3 | – |
713 | Isononylphenol, ethoxylated | 37205-87-1 | – |
714 | 4-Nonylphenol, branched, ethoxylated | 127087-87- 0 | – |
715 | Nonylphenol, branched, ethoxylated | 68412-54-4 | – |
716 | Octamethylcyclotetrasiloxane | 556-67-2 | – |
717 | Decamethylcyclopentasiloxane | 541-02-6 | – |
718 | Pentachloroethane | 76-01-7 | – |
719 | N2-benzyl pentachlorophenyl N2-carboxy-L-(2aminoglutaramate) | 13673-51-3 | – |
720 | Perchlorophenyl N-(benzyloxycarbonyl)-Lisoleucinate | 13673-53-5 | – |
721 | Perchlorophenyl S-benzyl-N- (benzyloxycarbonyl)-L-cysteinate | 13673-54-6 | – |
722 | Pentachlorophenol | 87-86-5 | – |
723 | Sodium pentachlorophenolate | 131-52-2 | – |
724 | Perchlorophenyl 5-oxo-L-prolinate | 28990-85-4 | – |
725 | Pentachlorophenyl laurate | 3772-94-9 | – |
726 | Potassium pentachlorophenolate | 7778-73-6 | – |
727 | Pentachlorophenyl N-[[(4- methoxyphenyl)methoxy]carbonyl]-L-serinate | 23234-97-1 | – |
728 | Zinc bis(pentachlorophenolate) | 2917-32-0 | – |
729 | Polybromobiphenyls, Polybrominatedbiphenyls (PBB) | 59536-65-1 | – |
730 | Benzo[a]pyrene (BaP) | 50-32-8 | – |
731 | Dibenzo[a,h]anthracene (DBAhA) | 53-70-3 | – |
732 | Benzo[a]anthracene (BaA) | 56-55-3 | – |
733 | Chrysen (CHR) | 218-01-9 | – |
734 | Benzo[j]fluoranthene (BjFA) | 205-82-3 | – |
735 | Benzo[b]fluoranthene (BbFA) | 205-99-2 | – |
736 | Benzo[k]fluoranthene (BkFA) | 207-08-9 | – |
737 | Benzo[e]pyrene (BeP) | 192-97-2 | – |
738 | Di-n-octyl phthalate (DNOP) | 117-84-0 | – |
739 | Di-―isodecyl‖ phthalate (DIDP) | 26761-40-0 | – |
740 | 1,2-Benzenedicarboxylic acid, di-C9-11-branched alkyl esters, C10-rich | 68515-49-1 | – |
741 | 1,2-Benzenedicarboxylic acid, di-C8-10-branched alkyl esters, C9-rich | 68515-48-0 | – |
742 | Di-―isononyl‖ phthalate (DINP) | 28553-12-0 | – |
743 | Toluene | 108-88-3 | – |
744 | Trichlorobenzene | 120-82-1 | – |
745 | Tris (2,3 dibromopropyl) phosphate | 126-72-7 | – |
746 | Tris(aziridinyl)phosphinoxide | 545-55-1 | – |
747 | Butyl bromoacetate | 18991-98-5 | – |
748 | Ethyl bromoacetate | 105-36-2 | – |
749 | Methyl bromoacetate | 96-32-2 | – |
750 | Propyl bromoacetate | 35223-80-4 | – |
Schedule III – Concerned Authorities
S. No. | Authorities with legal backing | Duties and corresponding Rule |
(1) | (2) | (3) |
1. | (a) Chief Inspector of Dock Safety appointed under the Dock Workers (Safety, Health and Welfare) Act, 1986 within the Dock area. (b) Chief Inspector of Mines appointed under the Mines Act, 1952 within the Mine area. (c) Atomic Energy Regulatory Board appointed under the Atomic Energy Act, 1972. (d) Chief Safety Officer appointed with concurrence of the Division for any Industrial Pocket notified under any central or state legislation. (e) Chairman CBIC for Customs Warehouses. (f) Chief Inspector of Factories appointed under the Factories Act, 1948 for areas for not covered under (a) to (e) above.
| Enforcement of direction and procedures in respect of industrial installations and isolated storages covered under their respective statutes and dealing with Hazardous Chemicals within their jurisdictions – (i) Approval and notification of Industrial Activities and Site Safety Report as per Rules 21, 22 and 23; (ii) Safety Audit Report as per Rules 24 to 26; (iii) Issuance of Improvement Notice under Rule 35; (iv) Notification of Chemical Accidents as per Rule 31; (v) Acceptance of On-site Emergency plans as per Rule 29; (vi) Preparation of off-site emergency plans in consultation with District Collector or District Emergency Authority in accordance with Rule 30; (vii) Analysis of a major accident under Rule 32. |
2. | Chief Inspector of Dock Safety appointed under the Dock Workers (Safety, Health and Welfare) Act, 1986. | All functions under Rule 27.
|
4. | Chief Controller of Explosives appointment under the Explosive Act, 1884. | Enforcement of all directions and procedures as mentioned in column (3) of Serial .No. 1 above, in respect of Industrial installations and isolated storages dealing with Hazardous Chemicals which are outside the jurisdiction of the Concerned Authorities set out in column (2) of |
|
| Serial No. 1 above and for all pipelines including inter-state pipelines. |
5. | The Chemical Regulatory Division. | Enforcement of Chapter III and Chapter V, as specified in Rule 36(1). |
6. | State Pollution Control Boards | Enforcement of Rule 21. |
Schedule IV – Substances Exempt for the purposes of Chapter III and V
S. No. | Name | CAS Number |
1. | Water, distilled, conductivity or of similar purity – H2O | 7732-18-5 |
2. | Starch
| 9005-25-8 |
3. | Fatty acids, coco, Me esters | 61788-59-8 |
4. | Cellulose pulp | 65996-61-4 |
5. | Syrups, corn, dehydrated | 68131-37-3 |
6. | Substances which result from a chemical reaction that occurs incidental to exposure of another substance or article to environmental factors such as air, moisture, microbial organisms or sunlight |
|
7. | Substances which result from a chemical reaction that occurs incidental to storage of another substance, mixture or article |
|
8. | Substances which result from a chemical reaction occurring upon end use of other substances, mixtures or articles, and which are not themselves manufactured, imported, or placed on the market. |
|
9. | Substances which occur in nature, if they are not chemically modified. For example, Minerals, ores, ore concentrates, raw and processed natural gas, crude oil, coal |
|
10. | Compost and biogas; Charcoal |
|
11. | Hydrogen and atmospheric Oxygen, Nitrogen and Noble gases |
|
12. | By-products, unless they are Imported or Placed in the Indian Market |
|
13. | Glass, Ceramic Fritz |
|
14. | Following Substances if not modified chemically: Liquified Petroleum Gas, Natural Gas Condensates, cement clinker, magnesium, coke |
|
15. | The following Substances when not chemically modified and obtained from natural sources, unless they fall within the definition of Priority Substances: Vegetable fats, oils and waxes, animal fats, oils and waxes, fatty acids from C6 to C24 and their potassium, sodium, calcium and magnesium salts and glycerol |
|
Schedule V – Information to be provided for Notification
1. Details of Notifier:
a. Name, address, phone, email of the Notifier
b. Name, address, phone, email of the person authorised to submit Notification
c. Details of foreign manufacturer, if the Notifier is an Importer or Authorised Representative
d. Location of the production and own use site(s), as appropriate
2. List main constituents of the substance with 10% (w/w) or more concentration
S.No. | IUPAC Name | Common Name | CAS No. | Molecular structure | Isomer | % age Conc. |
|
|
|
|
|
|
|
3. List all impurities with more than 1.0% but less than 10% (w/w) concentration
4. For substances of Unknown or Variable composition, Complex reaction products or Biological materials (UVCB), give the following details:
a. Structural representation of the constituents
b. Reaction scheme (including the identity of the reactants and the reaction type)
c. Process output (including identity of the precursors, the technology (method of preparation; process terms) and the typical composition)
5. Chemical Structural Details
a. Molecular wt.
b. Simplified Molecular Input Line Entry System (SMILES)
c. Information on optical activity and typical ratio of (stereo) isomers (if applicable and appropriate)
d. Spectral data:
i) High Performance Liquid Chromatography or Gas Chromatography or Gas Chromatography Mass Spectrometry or Liquid Chromatography Mass Spectrometry
ii) Infra Red spectra
iii) Ultra Violet-Vis Spectrophotometer – spectra
iv) Nuclear Magnetic Resonance
6. Hazard Classification of the Substance (according to eighth revision of UN-GHS)
7. Chemical uses
8. Name of known Downstream Users (at least top 3; will be kept confidential)
9. Actual quantity per annum in TPA (will be kept confidential under all circumstances)
10. Maximum Storage Capacity/Maximum quantity stored
(The information contained in the Notification must be based on test reports from NABL accredited labs or GLP labs or any other Published authentic study report.)
Schedule VI – Restricted or Prohibited Substances
Sr. No. | Chemical Name | CAS No. | Category |
1 | Phosgene |
| Restricted |
Schedule VII – Contents of Technical Dossier
1. Registrant Details:
a) Name of Legal Entity
b) Name of Submitter
c) Legal Representative of the Registrant
d) Contact details – address; phone; email
e) Location of site of production or use
f) Company Registration Number, if applicable
g) GST Number, if applicable
h) Plant site code, if applicable
2. Chemical identifiers
a) Chemical Name: IUPAC Name or Common/Trade Name or CAS Name
b) Chemical Numbers: CAS Number and IN Number / Notification number
c) Purity
d) Details of all impurities contained in concentrations of greater than 0.1% (w/w)
e) Nature of impurities, including isomers and by-products
f) Nature and order of magnitude (… ppm, … %) of any additives (e.g. stabilising agents or inhibitors)
3. Chemical Structural Details
a) Molecular wt.
b) SMILES
c) Molecular and structural formula
d) Information on optical activity and typical ratio of (stereo) isomers (if applicable and appropriate)
e) Spectral data:
i) High Performance Liquid Chromatography or Gas Chromatography or Gas Chromatography Mass Spectrometry or Liquid Chromatography Mass Spectrometry
ii) Infra Red spectra
iii) Ultra Violet-Vis Spectrophotometer – spectra
iv) Nuclear Magnetic Resonance
v) Mass spectrum
f) Type of substance – mono, multi, ‗Unknown or Variable Composition, Complex Products or of Biological Methods‘.
g) Description of the analytical methods or the appropriate bibliographical references for the identification of the substance and, where appropriate, for the identification of impurities and additives. This information shall be sufficient to allow the methods to be reproduced.
4. Identified Chemical uses
a) The calendar year of the registration
b) An indication of the tonnage used for his own use(s)
c) Form (substance, preparation or article) and/or physical state under which the substance is made available to downstream users.
d) Concentration or concentration range of the substance in preparations made available to downstream users and quantities of the substance in articles made available to downstream users.
e) Brief general description of the identified use(s)
f) Information on waste quantities and composition of waste resulting from manufacture of the substance, the use in articles and identified uses
g) description of the manufacturing process and
h) all identified uses that the Registrant wants to cover in accordance with use descriptors. (These uses shall be included in the Exposure Scenario (1 – 10 TPA) and Chemical Safety Report as the case may be.)
5. Classification and labelling information
a) The hazard classification of the substance(s),
b) The resulting hazard label for the substance(s)
c) Specific concentration limits, where applicable
6. Robust study summaries
7. Main use category:
a) industrial use and/or
b) professional use and/or
c) consumer use
8. Specification for industrial and professional use:
a) used in closed system and/or
b) use resulting in inclusion into or onto matrix and/or
c) non-dispersive use and/or
d) dispersive use
9. Significant route(s) of exposure:
Human exposure:
a) oral and/or
b) dermal and/or
c) inhalatory
10. Environmental exposure
a) water and/or
b) air and/or
c) solid waste and/or
d) soil
11. Pattern of exposure:
a) accidental/infrequent and/or
b) occasional and/or
c) continuous/frequent
Schedule VIII – Format for Chemical Safety Report
Part I
1. Summary of risk management measures
2. Declaration that risk management measures are implemented
3. Declaration that risk management measures are communicated
Part II
1. Identity of the substance and physical and chemical properties
2. Manufacture and uses
2.1. Manufacture
2.2. Identified uses
2.3. Uses advised against
3. Classification and labelling
4. Environmental fate properties
4.1. Degradation
4.2. Environmental distribution
4.3. Bioaccumulation
4.4. Secondary Poisoning
5. Human health hazard assessment
5.1. Toxicokinetics (absorption, metabolism, distribution and elimination)
5.2. Acute toxicity
5.3. Irritation
5.3.1. Skin
5.3.2. Eye
5.3.3. Respiratory Tract
5.4. Corrosivity
5.5. Sensitisation
5.5.1. Skin
5.5.2. Respiratory system
5.6. Repeated dose toxicity
5.7. Mutagenicity
5.8. Carcinogenicity
5.9. Toxicity for reproduction
5.9.1. Effects on fertility
5.9.2. Developmental Toxicity
5.10. Other effects
5.11. Derivation of Derived No-Effect Level(s) (DNELs)
6. Human health hazard assessment of physicochemical properties
6.1. Explosivity
6.2. Flammability
6.3. Oxidising potential
7. Environmental hazard assessment
7.1. Aquatic Compartment (including sediment)
7.2. Terrestrial Compartment
7.3. Atmospheric Compartment
7.4. Microbiological Activity in Sewage Treatment Systems
7.5. Derivation of Predicted No-Effect Concentration (PNEC)
8. Persistent, Bioaccumulative and Toxic (PBT) and very Persistent very Bioaccumulative (vPvB) assessment
9. Exposure assessment
9.1. [Title of Exposure Scenario 1]
9.1.1. Exposure Scenario
9.1.2. Exposure Estimation
9.2. [Title of Exposure Scenario 2]
9.2.1. Exposure Scenario
9.2.2. Exposure Estimation [etc.]
10. Risk characterisation
10.1. [Title of Exposure Scenario 1]
10.1.1. Human Health
10.1.1.1. Workers
10.1.1.2. Consumers
10.1.1.3. Indirect exposure to humans via the environment
10.1.2. Environment
10.1.2.1. Aquatic Compartment (incl. Sediment)
10.1.2.2. Terrestrial Compartment
10.1.2.3. Atmospheric Compartment
10.1.2.4. Microbiological Activity in Sewage Treatment Systems
10.2. [Title of Exposure Scenario 2]
10.2.1. Human Health
10.2.1.1. Workers
10.2.1.2. Consumers
10.2.1.3. Indirect exposure to humans via the environment
10.2.2. Environment
10.2.2.1. Aquatic Compartment (incl. Sediment)
10.2.2.2. Terrestrial Compartment
10.2.2.3. Atmospheric Compartment
10.2.2.4. Microbiological Activity in Sewage Treatment Systems
(If desired, Sections 9 and 10 may be combined into one Section without loss of information)
Schedule IX – Safety Data Sheet
The safety data sheet shall include the following 16 headings in the given sequence and in addition the subheadings are also listed; pictograms, hazard statements, warning and other relevant information are based upon the UN-GHS classification criteria.
Section 1: Identification of the substance/mixture and of the company/undertaking
1.1. Product identifier
1.2. Relevant identified uses of the substance or mixture and uses advised against
1.3. Details of the supplier of the safety data sheet
1.4. Emergency telephone number
Section 2: Hazards identification
2.1. Classification of the substance or mixture
2.2. Label elements
2.3. Other hazards
Section 3: Composition/information on ingredients
3.1. Substances
3.2. Mixtures
Section 4: First aid measures
4.1. Description of first aid measures
4.2. Most important symptoms and effects, both acute and delayed
4.3. Indication of any immediate medical attention and special treatment needed
Section 5: Fire fighting measures
5.1. Extinguishing media
5.2. Special hazards arising from the substance or mixture
5.3. Advice for fire fighters
Section 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
6.2. Environmental precautions
6.3. Methods and material for containment and cleaning up
6.4. Reference to other sections
Section 7: Handling
7.1. Precautions for safe handling
7.2. Conditions for safe storage, including any incompatibilities
7.3. Specific end use(s)
Section 8: Exposure controls/personal protection
8.1. Control parameters
8.2. Exposure controls
Section 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
9.2. Other information
Section 10: Stability and reactivity
10.1. Reactivity
10.2. Chemical stability
10.3. Possibility of hazardous reactions
10.4. Conditions to avoid
10.5. Incompatible materials
10.6. Hazardous decomposition products
Section 11: Toxicological information
11.1. Information on toxicological effects
Section 12: Ecological information
12.1. Toxicity
12.2. Persistence and degradability
12.3. Bioaccumulative potential
12.4. Mobility in soil
12.5. Results of PBT and vPvB assessment
12.6. Other adverse effects
12.7 Other Information
Section 13: Disposal considerations
13.1. Waste treatment methods
Section 14: Transport information
14.1. UN number
14.2. UN proper shipping name
14.3. Transport hazard class(es)
14.4. Packing group
14.5. Environmental hazards
14.6. Special precautions for user
14.7. Transport in bulk according to Annex II of Marpol and the IBC Code
Section 15: Regulatory information
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
15.2. Chemical safety assessment
Section 16: Legal Status of Substance
Information on legal status of the Substance in other jurisdictions, i.e. specifically information on whether the Substance has been restricted or prohibited under any other laws for the time being in force, or under any other jurisdiction.
Section 17: Other information
Including information on preparation and revision of Safety Data Sheet, sources of information.
Schedule X – Hazardous Chemicals
Part I. Major Accident Hazard Criteria
(a) Toxic Chemicals: Chemicals having the following values of acute toxicity and which owing to their physical and chemical properties, are capable of producing major accident hazards:
S. No. | Toxicity | Oral toxicity LD50(mg/kg) | Dermal toxicity LD50(mg/kg) | Inhalation toxicity LC50(mg/m3) |
1. | Extremely toxic | Less than 5 | Less than 40 | Less than 0.5 |
2. | Highly toxic | 5-50 | 40-200 | 0.5-2.0 |
3. | Toxic | 50-200 | 200-1000 | 2-10 |
(b) Flammable Chemicals:
(i) Flammable Gases: Gases which at 20oC and at standard atmospheric pressure of 101.3KPa are :-
Either
(a) ignitable when in a mixture of 13 percent or less by volume with air;
or
(b) have a flammable range with mixture of air of at least 12 percentage points regardless of the lower flammable limits.
Note: The flammability shall be determined by tests or by calculation in accordance with methods adopted by International Standards Organization ISO Number 10156 of 1990 or by Bureau of Indian Standard ISI Number 1446 of 1985.
(ii) Extremely Flammable Liquids: liquids which have flash point lower than or equal to 23oC and boiling point less than 35oC.
(iii) Very Highly Flammable Liquids: liquids which have a flash point lower than or equal to 23oC and initial boiling point higher than 35oC.
(iv) Highly Flammable Liquids: liquids which have a flash point lower than or equal to 60oC but higher than 23oC.
(v) Flammable Liquids: liquids which have a flash point higher than 60oC but lower than 90oC.
(c) Explosives: explosives mean a solid or liquid or pyrotechnic substance (or a mixture of substances) or an article;
Either
(a) which is in itself capable by chemical reaction of producing gas at such a temperature and pressure and at such a speed as to cause damage to surroundings;
or
(b) which is designed to produce an effect by heat, light, sound, gas or smoke or a combination of these as the result of non-detonative self-sustaining exothermic chemical reaction
Part II. List Of Hazardous Chemicals
NAME OF HAZARDOUS CHEMICALS
1. Acetaldehyde
2. Acetic acid
3. Acetic anhydride
4. Acetone
5. Acetone cyanohydrin
6. Acetone thiosemicarbazide
7. Acetonitrile
8. Acetylene
9. Acetylene tetra chloride
10. Acrolein
11. Acrylamide
12. Acrylonitrile
13. Adiponitrile
14. Aldicarb
15. Aldrin
16. Allyl alcohol
17. Allyl amine
18. Allyl chloride
19. Aluminium (powder)
20. Aluminium azide
21. Aluminium borohydride
22. Aluminium chloride
23. Aluminium fluoride
24. Aluminium phosphide
25. Amino diphenyl
26. Amino pyridine
27. Aminophenol-2
28. Aminopterin
29. Amiton
30. Amiton dialate
31. Ammonia
32. Ammonium chloro platinate
33. Ammonium nitrate
34. Ammonium nitrite
35. Ammonium picrate
36. Anabasine
37. Aniline
38. Aniline2,4, 6-Trimethyl
39. Anthraquinone
40. Antimony pentafluoride
41. Antimycin A 42. ANTU (Alpha-Naphthylthiourea)
43. Arsenic pentoxide
44. Arsenic trioxide
45. Arsenous trichloride
46. Arsine
47. Asphalt
48. Azinpho-ethyl
49. Azinphos methyl
50. Bacitracin
51. Barium azide
52. Barium nitrate
53. Barium nitride
54. Benzal chloride
55. Benzenamine,3-Trifluoromethyl
56. Benzene
57. Benzene sulfonyl chloride
58. Benzene. 1- (chloromethyl)-4 Nitro
59. Benzene arsenic acid
60. Benzidine
61. Benzidine salts
62. Benzimidazole. 4, 5-Dichloro-2 (Trifluoromethyl)
63. Benzoquinone-P
64. Benzotrichloride
65. Benzoyl chloride
66. Benzoyl peroxide
67. Benzyl chloride
68. Beryllium (Powder)
69. Bicyclo (2, 2, 1) Heptane -2- carbonitrile
70. Biphenyl
71. Bis (2-Chloroethyl) sulphide
72. Bis (Chloromethyl) Ketone
73. Bis (Tert-butyl peroxy) cyclohexane
74. Bis (Terbutylperoxy) butane
75. Bis(2,4, 6-Trinitrophenylamine)
76. Bis (Chloromethyl) Ether
77. Bismuth and compounds
78. Bisphenol-A
79. Bitoscanate
80. Boron Powder
81. Boron trichloride
82. Boron trifluoride
83. Boron trifluoride comp. With methylether, 1:1
84. Bromine
85. Bromine pentafluoride
86. Bromo chloro methane
87. Bromodialone
88. Butadiene
89. Butane
90. Butanone-2
91. Butyl amine tert
92. Butyl glycidyl ether
93. Butyl isovalerate
94. Butyl peroxymaleate tert
95. Butyl vinyl ether
96. Butyl-n-mercaptan
97. C.I.Basic green
98. Cadmium oxide
99. Cadmium stearate
100. Calcium arsenate
101. Calcium carbide
102. Calcium cyanide
103. Camphechlor (Toxaphene)
104. Cantharidin
105. Captan
106. Carbachol chloride
107. Carbaryl
108. Carbofuran (Furadan)
109. Carbon tetrachloride
110. Carbon disulphide
111. Carbon monoxide
112. Carbonphenothion
113. Carvone
114. Cellulose nitrate
115. Chloroacetic acid
116. Chlordane
117. Chlorofenvinphos
118. Chlorinated benzene
119. Chlorine
120. Chlorine oxide
121. Chlorine trifluoride
122. Chlormephos
123. Chlormequat chloride
124. Chloroacetal chloride
125. Chloroacetaldehyde
126. Chloroaniline -2
127. Chloroaniline -4
128. Chlorobenzene
129. Chloroethyl chloroformate
130. Chloroform
131. Chloroformyl morpholine
132. Chloromethane
133. Chloromethyl methyl ether
134. Chloronitrobenzene
135. Chlorophacinone
136. Chlorosulphonic acid
137. Chlorothiophos
138. Chloroxuron
139. Chromic acid
140. Chromic chloride
141. Chromium powder
142. Cobalt carbonyl
143. Cobalt Nitrilmethylidyne compound
144. Cobalt (Powder)
145. Colchicine
146. Copper and Compounds
147. Copperoxychloride
148. Coumafuryl
149. Coumaphos
150. Coumatetralyl
151. Crimidine
152. Crotenaldehyde
153. Crotonaldehyde
154. Cumene
155. Cyanogen bromide
156. Cyanongen iodide
157. Cyanophos
158. Cyanothoate
159. Cyanuric fluoride
160. Cyclo hexylamine
161. Cyclohexane
162. Cyclohexanone
163. Cycloheximide
164. Cyclopentadiene
165. Cyclopentane
166. Cyclotetramethylenetetranitramine
167. Cyclotrimethylenetrinnitramine
168. Cypermethrin
169. DDT
170. Decaborane (1:4)
171. Demeton
172. Demeton S-Methyl
173. Di-n-propyl peroxydicarbonate (Conc = 80%)
174. Dialifos
175. Diazodinitrophenol
176. Dibenzyl peroxydicarbonate (Conc>= 90%)
177. Diborane
178. Dichloroacetylene
179. Dichlorobenzalkonium chloride
180. Dichloroethyl ether
181. Dichloromethyl phenylsilane
182. Dichlorophenol – 2, 6
183. Dichlorophenol – 2, 4
184. Dichlorophenoxy acetic acid
185. Dichloropropane – 2, 2
186. Dichlorosalicylic acid-3, 5
187. Dichlorvos (DDVP)
188. Dicrotophos
189. Dieldrin
190. Diepoxy butane
191. Diethyl carbamazine citrate
192. Diethyl chlorophosphate
193. Diethyl ethtanolamine
194. Diethyl peroxydicarbonate (Conc=30%)
195. Diethyl phenylene diamine
196. Diethylamine
197. Diethylene glycol
198. Diethylene glycol dinitrate
199. Diethylene triamine
200. Diethleneglycol butyl ether
201. Diglycidyl ether
202. Digitoxin
203. Dihydroperoxypropane (Conc >=30%)
204. Diisobutyl peroxide
205. Dimefox
206. Dimethoate
207. Dimethyl dichlorosilane
208. Dimethyl hydrazine
209. Dimethyl nitrosoamine
210. Dimethyl P phenylene diamine
211. Dimethyl phosphoramidi cyanidic acid (TABUM)
212. Dimethylphosphorochloridothioate
213. Dimethyl sulfolane (DMS)
214. Dimethyl sulphide
215. Dimethylamine
216. Dimethylaniline
217. Dimethylcarbonyl chloride
218. Dimetilan
219. Dinitro O-cresol
220. Dinitrophenol
221. Dinitrotoluene
222. Dinoseb
223. Dinoterb
224. Dioxane-p
225. Dioxathion
226. Dioxine N
227. Diphacinone
228. Diphosphoramide octamethyl
229. Diphenyl methane di-isocynate (MDI)
230. Dipropylene Glycol Butyl ether
231. Dipropylene glycolmethyl ether
232. Disec-butyl peroxydicarbonate (Conc.>80%)
233. Dithiobiurate
234. Endosulfan
235. Endothion
236. Endrin
237. Epichlorohydrine
238. EPN
239. Ergocalciferol
240. Ergotamine tartarate
241. Ethanesulfenyl chloride, 2 chloro
242. Ethanol 1-2 dichloracetate
243. Ethion
244. Ethoprophos
245. Ethyl acetate
246. Ethyl alcohol
247. Ethyl benzene
248. Ethyl bis amine
249. Ethyl bromide
250. Ethyl carbamate
251. Ethyl ether
252. Ethyl hexanol -2
253. Ethyl mercaptan
254. Ethyl mercuric phosphate
255. Ethyl methacrylate
256. Ethyl nitrate
257. Ethyl thiocyanate
258. Ethylamine
259. Ethylene
260. Ethylene chlorohydrine
261. Ethylene dibromide
262. Ethylene diamine
263. Ethylene diamine hydrochloride
264. Ethylene flourohydrine
265. Ethylene glycol
266. Ethylene glycol dinitrate
267. Ethylene oxide
268. Ethylenimine
269. Ethylene di chloride
270. Femitrothion
271. Fensulphothion
272. Fluorine
273. Fluoro2-hyrdoxy butyric acid amid salt ester
274. Fluoroacetamide
275. Fluoroacetic acid amide salts and esters
276. Fluoroacetylchloride
277. Fluorobutyric acid amide salt esters
278. Fluorocrotonic acid amides salts esters
279. Fluorouracil
280. Fonofos
281. Formaldehyde
282. Formetanate hydrochloride
283. Formic acid
284. Formoparanate
285. Formothion
286. Fuberidazole
287. Furan
288. Gallium Trichloride
289. Glyconitrile (Hydroxyacetonitrile)
290. Guanyl-4-nitrosaminoguynyl-1-tetrazene
291. Heptachlor
292. Hexamethyl terta-oxyacyclononate (Conc 75%)
293. Hexachlorobenzene
294. Hexachlorocyclohexan (Lindane)
295. Hexachlorocyclopentadiene
296. Hexachlorodibenzo-p-dioxin
297. Hexachloronapthalene
298. Hexafluoropropanone sesquihydrate
299. Hexamethyl phosphoromide
300. Hexamethylene diamine N N dibutyl
301. Hexane
302. Hexanitrostilbene 2, 2, 4, 4, 6, 6
303. Hexene
304. Hydrogen selenide
305. Hydrogen sulphide
306. Hydrazine
307. Hydrazine nitrate
308. Hydrochloric acid
309. Hydrogen
310. Hydrogen bromide
311. Hydrogen cyanide
312. Hydrogen fluoride
313. Hydrogen peroxide
314. Hydroquinone
315. Indene
316. Indium powder
317. Indomethacin
318. Iodine
319. Iridium tetrachloride
320. Ironpentacarbonyl
321. Iso benzan
322. Isoamyl alcohol
323. Isobutyl alcohol
324. Isobutyro nitrile
325. Isocyanic acid 3, 4 dichlorophenyl ester
326. Isodrin
327. Isofluorophosphate
328. Isophorone diisocyanate
329. Isopropyl alcohol
330. Isopropyl chlorocarbonate
331. Isopropyl formate
332. Isopropyl methyl pyrazolyl dimethyl carbamate
333. Juglone (5-Hydroxy Naphthalene-1,4 dione)
334. Ketene
335. Lactonitrile
336. Lead arsenite
337. Lead at high temp (molten)
338. Lead azide
339. Lead styphanate
340. Leptophos
341. Liquified petroleum gas
342. Lithium hydride
343. N-Dinitrobenzene
344. Magnesium powder or ribbon
345. Malathion
346. Maleic anhydride
347. Malononitrile
348. Manganese Tricarbonyl cyclopentadiene
349. Mechlor ethamine
350. Mephospholan
351. Mercuric chloride
352. Mercuric oxide
353. Mercury acetate
354. Mercury fulminate
355. Mercury methyl chloride
356. Mesitylene
357. Methaacrolein diacetate
358. Methacrylic anhydride
359. Methacrylonitrile
360. Methacryloyl oxyethyl isocyanate
361. Methane
362. Methanesulphonyl fluoride
363. Methidathion
364. Methiocarb
365. Methonyl
366. Methoxy ethanol (2-methyl cellosolve)
367. Methoxyethyl mercuric acetate
368. Methyacryloyl chloride
369. Methyl 2-chloroacrylate
370. Methyl alcohol
371. Methyl amine
372. Methyl bromide (Bromomethane)
373. Methyl chloride
374. Methyl chloroform
375. Methyl chloroformate
376. Methyl cyclohexene
377. Methyl disulphide
378. Methyl ethyl ketone peroxide (Conc.60%)
379. Methyl formate
380. Methyl hydrazine
381. Methyl isobutyl ketone
382. Methyl isocyanate
383. Methyl isothiocyanate
384. Methyl mercuric dicyanamide
385. Methyl Mercaptan
386. Methyl Methacrylate
387. Methyl phencapton
388. Methyl phosphonic dichloride
389. Methyl thiocyanate
390. Methyl trichlorosilane
391. Methyl vinyl ketone
392. Methylene bis (2-chloroaniline)
393. Methylene chloride
394. Methylenebis-4,4(2chloroaniline)
395. Metolcarb
396. Mevinphos
397. Mezacarbate
398. Mitomycin C
399. Molybdenum powder
400. Monocrotophos
401. Morpholine
402. Mustard gas
403. N-Butyl acetate
404. N.-Butyl alcohol
405. N-Hexane
406. N- Methyl-N, 2, 4, 6-Tetranitroaniline
407. Naphtha
408. Nephtha solvent
409. Naphthalene
410. Naphthyl amine
411. Nickel carbonyl/nickel tetracarbonyl
412. Nickel powder
413. Nicotine
414. Nicotine sulphate
415. Nitric acid
416. Nitric oxide
417. Nitrobenzene
418. Nitrocellulose (dry)
419. Nitrochlorobenzene
420. Nitrocyclohexane
421. Nitrogen
422. Nitrogen dioxide
423. Nitrogen oxide
424. Nitrogen trifluoride
425. Nitroglycerine
426. Nitropropane-1
427. Nitropropane-2
428. Nitroso dimethyl amine
429. Nonane
430. Norbormide
431. O-Cresol
432. O-Nitro Toluene
433. O-Toludine
434. O-Xylene
435. O/P Nitroaniline
436. Oleum
437. OO Diethyl S ethyl suph. methyl phos
438. OO Diethyl S propythio methyl phosdithioate
439. OO Diethyl s ethtylsulphinyl methylphosphorothioate
440. OO Diethyl s ethylsulphonyl methylphosphorothioate
441. OO Diethyls ethylthiomethylphospho-rothioate
442. Organo rhodium complex
443. Orotic acid
444. Osmium tetroxide
445. Oxamyl
446. Oxetane, 3, 3-bis(chloromethyl)
447. Oxidiphenoxarsine
448. Oxy disulfoton
449. Oxygen (liquid)
450. Oxygen difluoride
451. Ozone
452. P-nitrophenol
453. Paraffin
454. Paraoxon (Diethyl 4 Nitrophenyl phosphate)
455. Paraquat
456. Paraquat methosulphate
457. Parathion
458. Parathion methyl
459. Paris green
460. Penta borane
461. Penta chloro ethane
462. Penta chlorophenol
463. Pentabromophenol
464. Pentachloro naphthalene
465. Pentadecyl-amine
466. Pentaerythriotol tetranitrate
467. Pentane
468. Pentanone
469. Perchloric acid
470. Perchloroethylene
471. Peroxyacetic acid
472. Phenol
473. Phenol, 2, 2-thiobis (4, 6-Dichloro)
474. Phenol, 2, 2-thiobis (4 chloro 6-methyl phenol)
475. Phenol, 3-(1-methyl ethyl) methylcarbamate
476. Phenyl hydrazine hydrochloride
477. Phenyl mercury acetate
478. Phenyl silatrane
479. Phenyl thiourea
480. Phenylene P-diamine
481. Phorate
482. Phosfolan
483. Phosgene
484. Phosmet
485. Phosphamidon
486. Phosphine
487. Phosphoric acid
488. Phosphoric acid dimethyl (4 methyl thio)phenyl
489. Phosphorthioic acid dimethyl S(2-Bis) Ester
490. Phosphorothioic acid methyl (ester)
491. Phosphorothioic acid, OO Dimethyl S-(2-methyl)
492. Phosphorothioic, methyl-ethyl ester
493. Phosphorous
494. Phosphorous oxychloride
495. Phosphorous pentaoxide
496. Phosphorous trichloride
497. Phosphorous penta chloride
498. Phthalic anhydride
499. Phylloquinone
500. Physostignine
501. Physostignine salicylate (1:1)
502. Picric acid (2, 4, 6- trinitrophenol)
503. Picrotoxin
504. Piperdine
505. Piprotal
506. Pirinifos-ethyl
507. Platinous chloride
508. Platinum tetrachloride
509. Potassium arsenite
510. Potassium chlorate
511. Potassium cyanide
512. Potassium hydroxide
513. Potassium nitride
514. Potiassium nitrite
515. Potassium peroxide
516. Potassium silver cyanide
517. Powdered metals and mixtures
518. Promecarb
519. Promurit
520. Propanesultone
521. Propargyl alcohol
522. Propargyl bromide
523. Propen-2-chloro-1 ,3-diou diacetate
524. Propiolactone beta
525. Propionitrile
526. Propionitrile, 3-chloro
527. Propiophenone, 4-amino
528. Propyl chloroformate
529. Propylene dichloride
530. Propylene glycol, allylether
531. Propylene imine
532. Propylene oxide
533. Prothoate
534. Pyrazoxon
535. Pyrene
536. Pyridine
537. Pyridine, 2-methyl-3-vinyl
538. Pyridine, 4-nitro-1-oxide
539. Pyriminil
540. Quinone
541. Rhodium trichloride
542. Salcomine
543. Sarin
544. Selenious acid
545. Selenium Hexafluoride
546. Selenium oxychloride
547. Semicarbazide hydrochloride
548. Silane (4-amino butyl) diethoxy-meth
549. Sodium
550. Sodium anthra-quinone-1-sulphonate
551. Sodium arsenate
552. Sodium arsenite
553. Sodium azide
554. Sodium cacodylate
555. Sodium chlorate
556. Sodium cyanide
557. Sodium fluoro-acetate
558. Sodium hydroxide
559. Sodium pentachloro-phenate
560. Sodium picramate
561. Sodium selenate
562. Sodium selenite
563. Sodium sulphide
564. Sodium tellorite
565. Stannane acetoxy triphenyl
566. Stilbine (Antimony hydride)
567. Strychnine
568. Strychnine sulphate
569. Styphinic acid (2, 4,6-trinitroresorcinol)
570. Styrene
571. Sulphoxide, 3-chloropropyl octyl
572. Sulphur dichloride
573. Sulphur dioxide
574. Sulphur monochloride
575. Sulphur tetrafluoride
576. Sulphur trioxide
577. Sulphuric acid
578. Tellurim (powder)
579. Tellurium hexafluoride
580. TEPP (Tetraethyl pyrophosphate)
581. Terbufos
582. Tert-Butyl alcohol
583. Tert-Butyl peroxy carbonate
584. Tert-Butyl peroxy isopropyl
585. Tert-Butyl peroxyacetate (Conc >=70%)
586. Tert-Butyl peroxypivalate (Conc >=77%)
587. Tert-Butyl peroxyiso-butyrate
588. Tetra hydrofuran
589. Terta methyl lead
590. Tetra nitromethane
591. Tetra-chlorodibenzo-p-dioxin, 1, 2, 3, 7, 8(TCDD)
592. Tetraethyl lead
593. Tetramethylene disulphotetramine
594. Thallic oxide
595. Thallium carbonate
596. Thallium sulphate
597. Thallous chloride
598. Thallous malonate
599. Thallous sulphate
600. Thiocarbazide
601. Thiocynamicacid, 2(Benzothiazolyethio) methyl
602. Thiofamox
603. Thiometon
604. Thionazin
605. Thionyl chloride
606. Thiophenol
607. Thiosemicarbazide
608. Thiourea (2 chloro-phenyl)
609. Thiourea (2-methyl phenyl)
610. Tirpate (2,4-dimethyl-1,3-di-thiolane)
611. Titanium powder
612. Titanium tetra-chloride
613. Toluene
614. Toluene -2,4-di-isocyanate
615. Toluene 2,6-di-isocyanate
616. Trans-1,4-di chloro-butene
617. Tri nitro anisole
618. Tri (Cyclohexyl) methylstannyl 1,2,4 triazole
619. Tri (Cyclohexyl) stannyl-1H-1, 2, 3-triazole
620. Triaminotrinitrobenzene
621. Triamphos
622. Triazophos
623. Tribromophenol 2, 4, 6
624. Trichloro napthalene
625. Trichloro chloromethyl silane
626. Trichloroacetyl chloride
627. Trichlorodichlorophenylsilane
628. Trichloroethyl silane
629. Trichloroethylene
630. Trichloromethane sulphenyl chloride
631. Trichloronate
632. Trichlorophenol 2, 3, 6
633. Trichlorophenol 2, 4, 5
634. Trichlorophenyl silane
635. Trichlorophon
636. Triethoxy silane
637. Triethylamine
638. Triethylene melamine
639. Trimethyl chlorosilane
640. Trimethyl propane phosphite
641. Trimethyl tin chloride
642. Trinitro aniline
643. Trinitro benzene
644. Trinitro benzoic acid
645. Trinitro phenetole
646. Trinitro-m-cresol
647. Trinitrotoluene
648. Tri-orthocresyl phosphate
649. Triphenyltin chloride
650. Tris(2-chloroethyl)amine
651. Turpentine
652. Uranium and its compounds
653. Valino mycin
654. Vanadium pentoxide
655. Vinyl acetate monomer
656. Vinyl bromide
657. Vinyl chloride
658. Vinyl cyclohexane dioxide
659. Vinyl fluoride
660. Vinyl norbornene
661. Vinyl toluene
662. Vinyledene chloride
663. Warfarin
664. Warfarin Sodium
665. Xylene dichloride
666. Xylidine
667. Zinc dichloropentanitrile
668. Zinc phosphide
669. Zr powder, Zr tetrachloride
Schedule XI – Isolated Storage At Installations Other Than Those Covered By Schedule XIII
(a) The threshold quantities set out below relate to each installation or group of installations belonging to the same occupier where the distance between installation is not sufficient to avoid, in foreseeable circumstances, any aggravation of major accident hazards. These threshold quantities apply in any case to each group of installations belonging to the same occupier where the distance between the installations is less than 500 metres.
(b) For the purpose of determining the threshold quantity of a Hazardous Chemical at an isolated storage, account shall also be taken of any Hazardous Chemical which is :-
(i) in that part of any pipeline under the control of the occupier having control of the site, which is within 500 metres of that site and connected to it;
(ii) at any other site under the control of the same occupier any part of the boundary of which is within 500 meters of the said site; and
(iii) in any vehicle, vessel, aircraft or hovercraft, under the control of the same occupier which is used for storage purpose either at the site or within 500 metres of it;
but no account shall be taken of any Hazardous Chemical which is in a vehicle, vessel, aircraft or a hovercraft used for transporting it.
S. No. | Chemicals | Threshold Quantities (tonnes)
| |
(1) | (2) | (3) | (4) |
1. | Acrylonitrile | 350 | 5,000 |
2. | Ammonia atmospheric | 60 | 600 |
| Pressurized | 1000 | 5000 |
3. | Ammonium nitrate (a) | 350 | 2,500 |
4. | Ammonium nitrate fertilizers (b) | 1,250 | 10,000 |
5. | Chlorine | 10 | 25 |
6. | Flammable gases as defined in Schedule X, paragraph (b) (i)
| 50 | 300 |
7. | Extremely flammable liquids as defined in Schedule X, paragraph (b) (ii)
| 5000 | 50,000 |
8. | Liquid oxygen | 200 | 2000 |
9. | Sodium chlorate | 25 | 250 |
10. | Sulphur dioxide | 20 | 500 |
11. | Sulphur trioxide | 15 | 100 |
S. No. | Chemicals | Threshold Quantities (tonnes)
| |
(1) | (2) | (3) | (4) |
12. | Carbonyl chloride | 0.750 | 0.750 |
13. | Hydrogen Sulphide | 5 | 50 |
14. | Hydrogen Fluoride | 5 | 50 |
15. | Hydrogen Cyanide | 5 | 50 |
16. | Carbon disulphide | 20 | 200 |
17. | Bromine | 50 | 500 |
18. | Ethylene oxide | 5 | 50 |
19. | Propylene oxide | 5 | 50 |
20. | 2-Propenal (Acrolein) | 20 | 200 |
21. | Bromomethane (Methyl bromide) | 20 | 200 |
22. | Methyl isocyanate | 0.150 | 0.150 |
23. | Tetraethyl lead or tetramethyl lead | 5 | 50 |
24. | 1,2 Dibromoethane (Ethylene dibromide) | 5 | 50 |
25. | Hydrogen chloride (liquefied gas) | 25 | 250 |
26. | Diphenyl methane di-isocyanate (MDI) | 20 | 200 |
27. | Toluene di-isocyanate (TDI) | 10 | 100 |
28. | Very highly flammable liquids as defined in Schedule X, paragraph (b) (iii) | 7,000 | 7,000 |
29. | Highly flammable liquids as defined in Schedule X, paragraph (b) (iv) | 10,000 | 10,000 |
30. | Flammable liquids as defined in Schedule X, paragraph (b) (v)
| 15,000 | 1,00,000 |
(a) This applies to ammonium nitrate and mixtures of ammonium nitrates where the nitrogen content derived from the ammonium nitrate is greater than 28 per cent by weight and to aqueous solutions of ammonium nitrate where the concentration of ammonium nitrate is greater than 90 per cent by weight.
(b) This applies to straight ammonium nitrate fertilizers and to compound fertilizers where the nitrogen content derived from the ammonium nitrate is greater than 28 per cent by weight (a compound-fertilizer contains ammonium nitrate together with phosphate and/or potash).
Schedule XII – List of Hazardous Chemicals for Application of Chapter IV
(a) The quantities set-out-below relate to each installation or group of installations belonging to the same occupier where the distance between the installations is not sufficient to avoid, in foreseeable circumstances, any aggravation of major-accident hazards. These quantities apply in any case to each group of installations belonging to the same occupier where the distance between the installations is less than 500 metres.
(b) For the purpose of determining the threshold quantity of a Hazardous Chemical in an industrial installation, account shall also be taken of any Hazardous Chemicals which is :-
(i) in that part of any pipeline under the control of the occupier have control of the site, which is within 500 metres off that site and connected to it;
(ii) at any other site under the control of the same occupier any part of the boundary of which is within 500 metres of the said site ; and
(iii) in any vehicle, vessel, aircraft or hovercraft under the control of the same occupier which is used for storage purpose either at the site or within 500 metres of it;
but no account shall be taken of any Hazardous Chemical which is in a vehicle, vessel, aircraft or hovercraft used for transporting it.
Part -I. Named Chemicals
S. No. | Chemicals | Threshold Quantity
| CAS Number | |
(1) | (2) | (3) | (4) | (5) |
| Group 1-Toxic Substances |
| ||
1. | Aldicarb | 100kg |
| 116-06-3 |
2. | 4-Aminodiphenyl | 1 kg |
| 92-67-1 |
3. | Amiton | 1 kg |
| 78-53-5 |
4. | Anabasine | 100 kg |
| 494-52-0 |
5. | Arseinc pentoxide, Arsenic (V) acid and salts | 500 kg |
| 1303-28-2 |
6. | Arsenic trioxide, Arsenic (III) acid and salts | 100 kg |
| 1327-53-3 |
7. | Arsine (Arsenic hydride) | 10kg |
| 7784-42-1 |
8. | Azinphos-ethyl | 100kg |
| 2642-71-9 |
9. | Azinphos-methyl | 100 kg |
| 86-50-0 |
10. | Benzidine | 1 kg |
| 92-87-5 |
11. | Benzidine salts | 1 kg |
| 117-61-3 |
12. | Beryllium (powders, compounds) | 10 kg |
| 7440-41-7 |
13. | Bis (2-chloroethyl) sulphide | 1 kg |
| 505-60-2 |
S. No. | Chemicals | Threshold Quantity
| CAS Number | |
(1) | (2) | (3) | (4) | (5) |
14. | Bis (chloromethyl) ether | 1 kg |
| 542-88-1 |
15. | Carbofuran | 100 kg |
| 1563-66-2 |
16. | Carbophenothion | 100 kg |
| 786-19-6 |
17. | Chlorefenvinphos | 100 kg |
| 470-90-6 |
18. | 4-(Chloroformyl) morpholine | 1 kg |
| 15159-40-7 |
19. | Chloromethyl methyl ether | 1 kg |
| 107-30-2 |
20. | Cobalt (metal, oxide, carbonates, sulphides, as powders) | 1 t |
|
|
21. | Crimidine | 100 kg |
| 535-89-7 |
22. | Cyanthoate | 100 kg |
| 3734-95-0 |
23. | Cycloheximide | 100 kg |
| 66-81-9 |
24. | Demeton | 100 kg |
| 8065-48-3 |
25. | Dialifos | 100 kg |
| 10311-84-9 |
26. | OO-Diethyl S-ethylsulphinylmethyl Phosphorothiate | 100 kg |
| 2588-05-8 |
27. | OO-Diethyl S-ethylsulphonylmethyl phosphorothiate | 100 kg |
| 2588-06-9 |
28. | OO-Diethyl S-ethylthiomethyl Phosphorothioate | 100 kg |
| 2600-69-3 |
29. | OO-Diethyl S-isoprophylthiomethyl phosphorodithioate | 100 kg |
| 78-52-4 |
30. | OO-Diethyl S-isopropylthiomethyl Phosphorodithioate | 100 kg |
| 3309-68-0 |
31. | Dimefox | 100 kg |
| 115-26-4 |
32. | Dimethylcarbamoyl chloride | 1 kg |
| 79-44-7 |
33. | Dimethylnitrosamine | 1 kg |
| 62-75-9 |
34. | Dimethyl phosphoramidocynacidic acid | 1 t |
| 77-81-6 |
35. | Diphacinone | 100 kg |
| 82-66-6 |
36. | Disulfoton | 100 kg |
| 298-04-4 |
37. | EPN | 100 kg |
| 2104-64-5 |
38. | Ethion | 100 kg |
| 563-12-2 |
39 | Fensulphothion | 100 kg |
| 115-90-2 |
40. | Fluenetil | 100 kg |
| 4301-50-2 |
41. | Fluoroacetic acid | 1 kg |
| 144-49-0 |
42. | Fluoroacetic acid, salts | 1 kg |
|
|
43. | Fluoroacetic acid, esters | 1 kg |
|
|
44. | Fluoroacetic acid, amides | 1 kg |
|
|
45. | 4-Fluorobutyric acid | 1 kg |
| 462-23-7 |
S. No. | Chemicals | Threshold Quantity
| CAS Number | |
(1) | (2) | (3) | (4) | (5) |
46. | 4-Fluorobutyric acid, salts | 1 kg |
|
|
47. | 4-Fluorobutyric acid, esters | 1 kg |
|
|
48. | 4-Fluorobutyric acid, amides | 1 kg |
|
|
49. | 4-Fluorobutyric acid | 1 kg |
| 37759-72-1 |
50. | 4-Fluorocrotonic acid, salts | 1 kg |
|
|
51. | 4-Fluorocrotonic acid, esters | 1 kg |
|
|
52. | 4-Fluorocrotonic acid, amides | 1 kg |
|
|
53. | 4-Fluoro-2-hydroxybutyric acid, amides | 1 kg |
|
|
54. | 4-Fluoro-2-hydroxybutyric acid, salts | 1 kg |
| 69780-81-0 |
55. | 4-Fluoro-2-hydroxybutyric acid, esters | 1 kg |
|
|
57. | Glycolonitrile (Hydroxyacetonitrile ) | 100 kg |
| 107-16-4 |
58. | 1,2,3,7,8,9-Hexachlorodibenzo-p-dioxin | 100 kg |
| 194-8-74-3 |
59. | Hexamethylphosphoramide | 1 kg |
| 680-31-9 |
60. | Hydrogen selenide | 10 kg |
| 7783-07-5 |
61. | Isobenzan | 100 kg |
| 297-78-9 |
62. | Isodrin | 100 kg |
| 465-73-6 |
63. | Juglone (5-Hydroxynaphithalene 1,4 dione) | 100 kg |
| 481-39-0 |
64. | 4,4-Methylenebis (2-chloroniline) | 10 kg |
| 101-14-4 |
65. | Methyl isocynate | 150 kg | 150kg | 624-83-9 |
66. | Mevinphos | 100 kg |
| 7786-34-7 |
67. | 2-Naphthylamine | 1 kg |
| 91-59-8 |
68. | 2-Nickel (metal, oxides, carbonates), sulphides, as powers) | 1 t |
|
|
69. | Nickel tetracarbonyl | 10 kg |
| 13463-39-3 |
70. | Oxygendisulfoton | 100 kg |
| 2497-07-6 |
71. | Oxygen difluoride | 10 kg |
| 7783-41-7 |
72. | Paraoxon (Diethyl 4-nitrophenyl phosphate) | 100 kg |
| 311-45-5 |
73. | Parathion | 100 kg |
| 56-38-2 |
74. | Parathion-methyl | 100 kg |
| 298-00-0 |
75. | Pentaborane | 100 kg |
| 19624-22-7 |
76. | Phorate | 100 kg |
| 298-02-2 |
77. | Phosacetim | 100 kg |
| 4104-14-7 |
78. | Phosgene (carbonyl chloride) | 750 kg | 750kg | 75-44-5 |
79. | Phosphamidon | 100 kg |
| 13171-21-6 |
80. | Phosphine (Hydrogen phosphide) | 100 kg |
| 7803-51-2 |
81. | Promurit (1-(3,4 dichlorophenyl)-3- | 100 kg |
| 5836-73-7 |
S. No. | Chemicals | Threshold Quantity
| CAS Number | |
(1) | (2) | (3) | (4) | (5) |
| triazenthiocarboxamide) |
|
|
|
82. | 1,3-Propanesultone | 1 kg |
| 1120-71-4 |
83. | 1-Propen-2-chloro-1,3diol diacetate | 10 kg |
| 10118-72-6 |
84. | Pyrazoxon | 100 kg |
| 108-34-9 |
85. | Selenium hexafluoride | 10 kg |
| 7783-79-1 |
86. | Sodium selenite | 100 kg |
| 10102-18-8 |
87. | Stibine (Antimony hydride) | 100 kg |
| 7803-52-3 |
88. | Sulfotep | 100 kg |
| 3689-24-5 |
89. | Sulphur dichloride | 1 t |
| 10545-99-0 |
90. | Tellurium hexafluoride | 100 kg |
| 7783-80-4 |
91. | TEPP | 100 kg |
| 107-49-3 |
92. | 2,3,7,8,-Tetrachlorodibenzo-p-dioxin (TCDD) | 1 kg |
| 1746-01-6 |
93. | Tetramethylene disulphotetramine | 1 kg |
| 80-12-6 |
94. | Thionazin | 100 kg |
| 297-97-2 |
95. | Tirpate (2,4-Dimethyl-1,3-dithiolane-2carboxaldehyde O-methylcarbamoyloxime) | 100 kg |
| 26419-73-8 |
96. | Trichloromethanesulphonyl chloride | 100 kg |
| 594-42-3 |
97. | 1-Tri (cyclohexyl) stannyl 1H-1,2,4- Triazole | 100 kg |
| 41083-11-8 |
98. | Triethylene melamine | 10 kg |
| 51-18-3 |
99. | Warfarin | 100 kg |
| 81-81-2 |
Group-2 Toxic Substances | ||||
100 | Acetone cyanohydrin (2-Cyanopropan- 2-ol | 200 t |
| 75-86-5 |
101 | Acrolein (2-Propenal) | 20 t | 200t | 107-02-8 |
102 | Acrylonitrile | 20 t | 200t | 107-13-1 |
103 | Allyl alcohol (Propen-1-ol) | 200 t |
| 107-18-6 |
104 | Allyl amine | 200 t |
| 107-11-9 |
105 | Ammonia | 50 t | 500t | 7664-41-7 |
106 | Bromine | 40 t | 500t | 7726-95-6 |
107 | Carbon disulphide | 20 t | 200t | 75-15-0 |
108 | Chlorine | 10 t | 25t | 7782-50-5 |
109 | Diphneyl methane di-isocynate (MDI) | 20 t | 200t | 101-68-8 |
110 | Ethylene dibromide (1,2- Dibromoethane) | 5 t | 50t | 106-93-4 |
111 | Ethyleneimine | 5 t |
| 151-56-4 |
S. No. | Chemicals | Threshold Quantity
| CAS Number | |
(1) | (2) | (3) | (4) | (5) |
112 | Formaldehyde (concentration <90%) | 5 t | 50t | 50-00-0 |
113 | Hydrogen chloride (liquified gas) | 25 t | 250t | 7647-01-0 |
114 | Hydrogen cyanide | 5 t | 20t | 74-90-8 |
115 | Hydrogen fluoride | 5 t | 50t | 7664-39-3 |
116 | Hydrogen sulphide | 5 t | 50t | 7783-06-4 |
117 | Methyl bromide (Bromomethane) | 20 t | 200 t | 74-83-9 |
118 | Nitrogen oxides | 50 t |
| 10024-97-2 |
119 | Propyleneimine | 50 t |
| 75-55-8 |
120 | Sulphur dioxide | 20 t | 250t | 7446-09-5 |
121 | Sulphur trioxide | 15 t | 75t | 7446-11-9 |
122 | Tetraethyl lead | 5 t | 200t | 78-00-2 |
123 | Tetra methyl lead | 5 t | 100t | 75-74-1 |
124 | Toluene di-isocynate (TDI) | 10 t
| 100 t | 584-84-9 |
Group-3 Highly Reactive Substances | ||||
125 | Acetylene (ethyne) | 5 t |
| 74-86-2 |
126 | a. Ammonium nitrate (1) b. Ammonium nitrate in form of fertilizer (2) | 350t 1250 t | 2500t 10,000 t | 6484-52-2 |
127 | 2,2 Bis (tert-butylperoxy) butane) (concentration >70%) | 5 t |
| 2167-23-9 |
128 | 1, 1-Bis(tert-butylperoxy) cyclohexane (concentration > 80%) | 5 t |
| 3006-86-8 |
129 | tert-Butyle proxyacetate (concentration ≤70% ) | 5 t |
| 107-71-1 |
130 | tert-Butyle peroxy isobutyrate (concentration >80%) | 5 t |
| 109-13-7 |
131 | Tert-Butyl peroxy isopropyl carbonate (concentration ≥80%) | 5 t |
| 2372-21-6 |
132 | Tert-Butyl peroxymaletate (concentration ≥80%) | 5 t |
| 1931-62-0 |
133 | Tert-Butyl peroxypivalate (concentration ≥77%) | 50 t |
| 927-07-1 |
134 | Dibenzyl peroxydicarbonate (concentration≥90%) | 5 t |
| 2144-45-8 |
135 | Di-sec-butyl peroxydicarbonate (concentration ≥80%) | 5 t |
| 19910-65-7 |
136 | Diethyl peroxydicarbonate (concentration ≥30% ) | 50 t |
| 14666-78-5 |
S. No. | Chemicals | Threshold Quantity
| CAS Number | |
(1) | (2) | (3) | (4) | (5) |
137 | 2,2-dihydroperoxypropane (concentration≥30%) | 5 t |
| 2614-76-08 |
138 | di-isobutyrl peroxide (concentration ≥50%) | 50 t |
| 3437-84-1 |
139 | Di-n-propyl peroxydicarbonate (concentration≥80%) | 5 t |
| 16066-38-9 |
140 | Ethylene oxide | 5 t | 50 t | 75-21-8 |
141 | Ethyl nitrate | 50 t |
| 625-58-1 |
142 | 3,3,6,6,9,9 Hexamethyl – 1,2,4 5-tert oxacycloxonane (concenttation ≥75%) | 50 t |
| 22397-33-7 |
143 | Hydrogen | 2 t | 50 t | 1333-74-0 |
144 | Liquid Oxygen | 200 t | 2000t | 7782-44-7 |
145 | Methyl ethyl ketone peroxide (concentration ≥60%) | 5 t |
| 1338-23-4 |
146 | Methyl isobutyl ketone peroxide (concentration ≥60%) | 50 t |
| 37206-20-5 |
147 | Peracetic acid (concentration ≥60%) | 50 t |
| 79-21-0 |
148 | Propylene oxide | 5 t | 50t | |
149 | Sodium chlorate | 25 t | 250 t | |
Group 4-Explosive Substances | ||||
150 | Barium azide | 1 [100] kg |
| |
151 | Bis(2,4,6 -trinitrophenyl) amine | 50 t |
| |
152 | Chlorotrinitro benzene | 50 t |
| |
153 | Cellulose nitrate (containing 12.6% Nitrogen) | 50 t |
| |
154 | Cyclotetramethylene teranitramine | 50 t |
| |
155 | Cyclotrimethylene trinitramine | 50 t |
| |
156 | Diazodinitrophenol | 10 t |
| |
157 | Diethylene glycol dinitrate | 10 t |
| |
158 | Dinitrophenol, salts | 50 t |
| |
159 | Enthylene glycol dinitrate | 10 t |
| |
160 | 1-Gyanyl-4-nitrosaminoguanyl-1tetrazene | 100 kg |
| |
161 | 2, 2, 4, 4, 6, 6, -: Hexanitrostilbene | 50 t |
| 20062-22-0 |
162 | Hydrazine nitrate | 50 t |
| 13464-97-6 |
163 | Lead azide | 100 kg |
| 13424-46-9 |
164 | Lead Styphnate (Lead 2,4,6- | 50 t |
| 15245-44-0 |
S. No. | Chemicals | Threshold Quantity
| CAS Number | |
(1) | (2) | (3) | (4) | (5) |
| trinitroresorcinoxide) |
|
|
|
165 | Mercury fuliminate | 10 t |
| 628-86-4 |
166 | N-Methyl-N,2,4,6-tetranitroaniline | 50 t |
| 479-45-8 |
167 | Nitroglycerine | 10 t | 10t | 55-63-0 |
168 | Pentaerythritol tetra nitrate | 50 t |
| 78-11-5 |
169 | Picric acid, (2,3,6-Trinitrophenol) | 50 t |
| 88-89-1 |
170 | Sodium picramate | 50 t |
| 831-52-7 |
171 | Styphnic acid (2,4,6-Trinitroresorcinol) | 50 t |
| 82-71-3
|
172 | 1,3,5-Triamino-2,4,6-Trinitrobezene | 50 t |
| 3058-38-6 |
173 | Trinitroaniline- | 50 t |
| 26952-42-1 |
174 | 2,4,6-Trinitroanisole | 50 t |
| 606-35-9 |
175 | Trinitrobenze | 50 t |
| 99-35-4 |
176 | Trinitrobenzoic acid | 50 t |
| 35860-50-5 129-66-8 |
177 | Trinitrocresol | 50 t |
| 28905-71-7 |
178 | 2,4,6-Trinitrophenetole | 50 t |
| 4732-14-3 |
179 | 2,4,6-Trinitrotoluene | 50 t | 50 t | 118-96-7 |
Part II. Classes Of Substances As Defined In Part – I, Schedule X and Not Specifically Named In Part –I Of This Schedule
S. No. | Chemicals | Threshold Quantity(tonnes)
| |
| Group 5 – Flammable Substances | ||
(1) | (2) | (3) | (4) |
1. | Flammable Gases | 15t | 200t |
2. | Extremely flammable liquids | 1000t | 5000t |
3. | Very highly flammable liquids | 1500t | 10000t |
4. | Highly Flammable liquids which remains liquid under pressure | 25t | 200t |
5. | Highly Flammable liquids | 2500t | 20000t |
6. | Flammable liquids | 5000t | 50000t |
(1) This applies to ammonium nitrate and mixtures of ammonium nitrate where the nitrogen content derived from the ammonium nitrate is greater than 28% by weight and aqueous solutions of ammonium nitrate where the concentration of ammonium nitrate is greater than 90% by weight.
(2) This applied to straight ammonium nitrate fertilizers and to compound fertilizers where the nitrogen content derived from the ammonium nitrate is greater than 28% by weight (a compound fertilizer contains ammonium nitrate together with phosphate and/or potash).
Schedule XIII – Industrial Installations
1. Installation for the production, processing or treatment of organic or inorganic chemicals used for this purpose, among others:
(a) Alkylation
(b) Amination by ammonolysis
(c) Carbonylation
(d) Condensation
(e) Dehydrogenation
(f) Esterification
(g) Halogenation and manufacture of halogens
(h) Hydrogenation
(i) Hydrolysis
(j) Oxidation
(k) Polymerziation
(l) Sulphonation
(m) Desulphurization, manufacture and transformation of sulphur containing compounds
(n) Nitration and manufacture of nitrogen containing compounds
(o) Manufacture of phosphorous-containing compounds
(p) Formulation of pesticides and of pharmaceutical products
(q) Distillation
(r) Extraction
(s) Solvation
(t) Mixing
2. Installation for distillation, refining or other processing of petroleum or petroleum products.
3. Installations for the total or partial disposal of solid or liquid substances by incineration or chemical decomposition. Steps to be taken for remedial action
4. Installations for production, processing, use or treatment of energy gases, for example, Liquefied Petroleum Gas, Liquefied Natural Gas, Substitute Natural Gas.
5. Installation for the dry distillation of coal or lignite.
6. Installations for the production of metals or non-metals by a wet process or by means of electrical energy of any other similar process.
Schedule XIV – Information To Be Furnished By The Occupier
1. The name, contact details and address of the Occupier
Part I
Subpart A
Report to be furnished for the Notification of the Industrial Activity
1. The full postal address of the site where the industrial activity will be carried on.
2. The area of the site covered by the notification and of any adjacent site which is required to be taken into account.
3. The date on which it is anticipated that the industrial activity will commence, or if it has already commenced a statement to that effect.
4. The name, physical state and maximum quantity of Hazardous Chemicals liable to be on the site.
5. Organisation structure namely organisation diagram set up for the proposed industrial activity and for ensuring safety.
6. Description of the industrial activity, namely-
a. construction design
b. protection zones explosion protection, separation distances
c. accessibility of plant
d. maximum number of persons working on the site and particularly of those persons exposed to be the hazard
e. flow diagram
7. Information relating to the site
namely-
a. a map of the site and its surrounding area to a scale large enough to show any features that may be significant in the assessment of the hazard or risk associated with the site
b. population distribution in the vicinity
c. a scale plan of the site showing the location and quantities of all significant inventories of the Hazardous Chemicals
d. a description of the process or storage involving the Hazardous Chemicals and an indication of the conditions under which they are normally held
e. the maximum number of persons likely to be present on site and particularly of those persons exposed to the hazard.
8. The arrangement for training of workers and maintaining equipment necessary to ensure the safety of such workers.
Subpart B
Particulars to be included regarding pipeline
1. The full postal address of the place-
a. from which the pipeline activity is controlled,
b. where the pipeline starts,
c. where the pipeline finishes
2. A map showing the pipeline route drawn to a scale of not less than 1:4,00,000.
3. The date on which it is anticipated that the notifiable activity will commence, or if it is already commenced a statement to that effect.
4. The total length of the pipeline, its diameter and normal operating pressure and the name and maximum quantity liable to be in the pipeline of Hazardous Chemicals for which notification is being made.
Part II
Information To Be Furnished In A Safety Report
1. The name and address of the person furnishing the information.
2. Description of the processes, namely –
(a) technical purpose of the industrial activity,
(b) basic principles of the technological process,
(c) process and safety -related data for the individual process stages,
(d) process description,
(e) Safety-related types of utilities.
3. Description of the Hazardous Chemicals, namely –
(a) chemicals (quantities, substance data, safety-related data, toxicological data and threshold values),
(b) the form in which the chemical may occur on or into which they may be transformed in the event of abnormal conditions,
(c) the degree of purity of the Hazardous Chemical.
4. Information on the preliminary hazard analysis, namely-
(a) hazards,
(b) types of accident
(c) system elements or events that can lead to a major accident,
(d) safety-relevant components.
5. Description of safety -relevant units, among others:
(a) special design criteria,
(b) controls and alarms,
(c) special relief systems,
(d) quick-acting valves,
(e) collecting tanks/dump tank,
(f) sprinkler system,
(g) firefighting etc.
6. Information on the hazard assessment, namely-
(a) identification of hazards ,
(b) the cause of major accidents,
(c) assessment of hazards according to their occurrence frequency,
(d) assessment of accident consequences,
(e) safety systems,
(f) known accident history.
7. Description of information or organizational systems used to carry on the industrial activity safely, namely-
(a) maintenance and inspection schedules,
(b) guidelines for the training of personnel,
(c) allocation and delegation of responsibility for plant safety,
(d) implementation of safety procedure.
of workers with probability of hazardous exposure and likely health outcomes following hazard evaluation and assessment.
8. Information on assessment of the consequences of major accidents, namely-
(a) assessment of the possible release of Hazardous Chemicals or of energy,
(b) possible dispersion of released chemical,
(c) assessment of the effects of the releases (size of the affected area, health effects, property damage)
(d) Exposure scenario constructed in the event of spill, fall out of pollutants and likely adverse health effects with a plan to follow up the exposed population.
9. Information on the mitigation of major accidents, namely –
(a) fire brigade,
(b) alarm systems,
(c) emergency plan containing system of organisation used to fight the emergency, the alarm and the communication rules guidelines for fighting the emergency, information about Hazardous Chemicals, examples of possible accident sequences,
(d) coordination with the District Emergency authority and its off-site emergency plan,
(e) notification of the nature and scope of the hazard in the event of an accident,
(f) antidotes in the event of a release of a Hazardous Chemical.
Part – III
Details to be Furnished in the On-site Emergency Plan
1. Name and address of the person furnishing the information.
2. Key personnel of the organization and responsibilities assigned to them in case of an emergency
3. Outside organization if involved in assisting during on-site emergency:
(a) Type of accidents
(b) Responsibility assigned
4. Details of liaison arrangement between the organizations.
5. Information on the preliminary hazard analysis:
(a) Type of accidents
(b) System elements or events that can lead to a major accident
(c) Hazards
(d) Safety relevant components
(e) Steps to be taken for remedial action
6. Details about the site:
(a) Location of dangerous substances
(b) Seat of key personnel
(c) Emergency control room
7. Description of Hazardous Chemicals at plant site:
(a) Chemicals (Quantities and toxicological data)
(b) Transformation if any, which could occur
(c) Purity of Hazardous Chemicals.
8. Likely dangers to the plant.
9. Enumerate effects of:
(i) Stress and strain caused during normal operation:
(ii) Fire and explosion inside the plant and effect if any, of fire and explosion outside.
10. Details regarding:
(i) Warning, alarm and safety and security systems.
(ii) Alarm and hazard control plans in line with disaster control and hazard control planning, ensuring the necessary technical and organizational precautions.
(iii) Reliable measuring instruments, control units and servicing of such equipment.
(iv) Precautions in designing of the foundation and load bearing parts of the building.
(v) Continuous surveillance of operations.
(vi) Maintenance and repair work according to the generally recognized rules of good engineering practices.
11. Details of communication facilities available during emergency and those required for an off-site emergency.
12. Details of firefighting and other facilities available and those required for an off-site emergency.
13. Details of first aid and hospital services available and its adequacy.
Schedule XV – Details to be Furnished in the Off-site Emergency Plan
1. The types of accidents and release to be taken into account.
2. Organizations involved including key personnel and responsibilities and liaison arrangements between them.
3. Information about the site including likely locations of dangerous substances, personnel and emergency control rooms.
4. Technical information such as chemical and physical characteristics and dangers of the substances and plant.
5. Identify the facilities and transport routes.
6. Contact for further advice e.g. meteorological information, transport, temporary food and accommodation, first aid and hospital services, water and agricultural authorities.
7. Communication links including telephones, radios and standby methods.
8. Special equipment including firefighting materials, damage control and repair items.
9. Details of emergency response procedures.
10. Notify the public.
11. Evacuation arrangements.
12. Arrangements for dealing with the press and other media interests
13. Longer term clean up.
Schedule XVI – Information to be furnished regarding Notification of a Chemical Accident
1. General data
(a) Name of the site of Major Chemical Accident
(b) Name, contact details and address of the Occupier
(c) (i) Registration number
(ii) Licence number (as may have been allotted under any status applicable to the site, e.g. the Factories Act)
(d) (i) Nature of industrial activity
2. Type of major accident
(a) Explosion
(b) Fire
(c) Emission of dangerous substance
(d) Other
3. Substance(s) emitted
4. Description of the major accident
(a) Date, shift and hour of the accident
(b) Department/Section and exact place where
the accident took place
(c) The process/operation undertaken in the
Department/Section where the accident took place.
(d) The circumstances of the accident and
the dangerous substance involved
5. Causes of the major accident.
(a) Known (to be specified)
(b) Not Known
(c) Information will be supplied as soon as possible
6. Sequence of event in chronological order including information given to authorities/public etc.
7. Nature and extent of damage
(a) Within the establishment casualties
1) Killed
2) Injured
3) Poisoned
4) Persons exposed to the major accident
5) material damaged
6) danger is still present
7) danger no longer exists.
(b) Outside the establishment casualties.
1) Killed
2) Injured
3) Poisoned
4) Persons exposed to the major accident
5) Material damaged
6) Damage to environment
7) The danger is still present
8) The danger no longer exists
8. Data available for assessing the effects of the accident on persons and environment.
9. Emergency Measures taken and measures envisaged to be taken to alleviate short term effects of the accident.
10. Steps already taken or envisaged
(a) to alleviate medium- or long-term effects of the accident
(b) to prevent recurrence of similar major accident
(c) any other relevant information.
Schedule XVII – Information in Labelling
A Priority Substance in packaging shall bear a label including the following elements:
1. The name, address and telephone number of the manufacturer, importer or downstream user
2. The nominal quantity (with +/- 5% accuracy) of the Priority Substance or Hazardous Chemical in concentration of greater than 0.1% (w/w) in the package made available to the general public, unless this quantity is specified elsewhere on the package
3. Product identifiers
4. Hazard pictograms where applicable
5. Signal words, where applicable
6. Hazard statements, where applicable,
7. Appropriate precautionary statements, where applicable
8. A section, where applicable
9. IN Number as assigned by the Division
(All information shall be in accordance to the eighth revision of UN-GHS Classification)
Schedule XVIII – Format of Certificates
Part A- Notification Certificate
Notification Certificate
issued under Rule 8 of the Chemicals (Management & Safety Rules), 20xx
Name of the Notifier:
Name of the Substance:
Chemical Composition of Substance:
Tonnage Band that the Substance falls under:
Notification Number:
Notification Date:
Comments:
Issued by
Head, Chemical Regulatory Division Petroleum and Explosives Safety Organisation
Part B – Registration Certificate
Registration Certificate
issued under Rule 10 of the Chemicals (Management & Safety Rules), 20xx
Name of Registrant:
Name of the Substance:
Chemical Composition of Substance:
Tonnage Band that the Substance falls under:
Notification Number:
Registration Number:
Registration Date:
Comments:
Issued by Head, Chemical Regulatory Division
Schedule XIX – Fees and Fines Payable
1. Fees for Notifiers and Registrants under the Rules generally (Rs. ‘000)
S. No. | Rule |
| Amount payable by MSMEs | Amount payable by all other entities | |
1. | 8(5) | Notification by tonnage band | 1 – 10 TPA | 10 | 25 |
10 – 100 TPA | 30 | 75 | |||
100 – 1000 TPA | 80 | 200 | |||
> 1000 TPA | 250 | 600 | |||
2. | 10(10) | Registration by tonnage band | 1 – 10 TPA | 15 | 37 |
10 – 100 TPA | 45 | 112 | |||
100 – 1000 TPA | 120 | 300 | |||
> 1000 TPA | 375 | 900 | |||
3. | 16(5) | Request for authorization for use of a Restricted Substance | 1000 | 1000 | |
4. | 17(3) | Request for Confidentiality | 5 | 100 | |
5. | 19(4) | Filing an appeal | 10 | 100 | |
2. Fees for updating tonnage band in Notifications and Registrations (Rs.‟000)
S. No. | Rule |
|
| Amount payable by MSMEs | Amount payable by all other entities |
1 | 8(5) . | Updating tonnage band in Notification | From 1 – 10 TPA to 10 -100 TPA | 20 | 50 |
From 1 – 10 TPA to 100 -1000 TPA | 70 | 175 | |||
From 1 – 10 TPA to >1000 TPA | 240 | 575 | |||
From 10 – 100 TPA to 100 -1000 TPA | 50 | 125 | |||
From 10 – 100 TPA to >1000 TPA | 220 | 525 | |||
From 100 – 1000 TPA to >1000 TPA | 170 | 400 |
3. Fees for Joint Registration per Registrant (Rs.”000)
S. No. | Rule | Tonnage Band | Amount payable by MSMEs | Amount payable by all other entities |
1. | 10(10) | 1 – 10 TPA | 10 | 25 |
10 – 100 TPA | 30 | 75 | ||
100 – 1000 TPA | 80 | 200 | ||
>1000 TPA | 250 | 600 |
4. Sitting Fees for Members of Scientific Committee and Risk Assessment Committee (Rs. „000)
S. No | Rule | Amount per day |
1. | 4(7) | 10 |
5. Fines (Rs. „000)
S. No | Rule | Tonnage Band | Fine to be imposed for each day of contravention |
1. | 35(1) & (2) | 1 – 1000 TPA | 25 |
2. | 35(1) & (2) | >1000 TPA | 50 |